Asymmetric hydrogenation with perfluoroalkylated monodentate phosphorus(III) ligands in supercritical CO2 and CH2Cl2

被引：18

作者：

Adams, DJ ^{[1
]}

Chen, WP

Hope, EG

Lange, S

Stuart, AM

West, A

Xiao, JL

机构：

[1] Univ Leicester, Dept Chem, Leicester LE1 7RH, Leics, England

[2] Univ Liverpool, Leverhulme Ctr Innovat Catalysis, Dept Chem, Liverpool L69 7ZD, Merseyside, England

来源：

GREEN CHEMISTRY | 2003年 / 5卷 / 02期

关键词：

D O I：

10.1039/b212313b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Four chiral perfluoroalkylated monodentate phosphorus( III) ligands have been prepared and characterised. These ligands have been evaluated in the rhodium-catalysed asymmetric hydrogenation of dimethyl itaconate in both dichloromethane and supercritical CO2 (scCO(2)) and compared with the parent, non-perfluoroalkylated, catalyst systems.

引用

页码：118 / 122

页数：5

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