Bringing an "Old" Biological Buffer to Coordination Chemistry: New 1D and 3D Coordination Polymers with [Cu4(Hbes)4] Cores for Mild Hydrocarboxylation of Alkanes

被引：75

作者：

Kirillov, Alexander M. ^{[1
]}

Coelho, Jaime A. S. ^{[1
]}

Kirillova, Marina V. ^{[1
]}

da Silva, M. Fatima C. Guedes ^{[1
,2
]}

Nesterov, Dmytro S. ^{[1
]}

Gruenwald, Katrin R. ^{[1
]}

Haukka, Matti ^{[3
]}

Pombeiro, Armando J. L. ^{[1
]}

机构：

[1] Univ Tecn Lisboa, Inst Super Tecn, Ctr Quim Estrutural, P-1049001 Lisbon, Portugal

[2] Univ Lusofona Humanidades & Technol, ULHT Lisbon, P-1749024 Lisbon, Portugal

[3] Univ Eastern Finland, Dept Chem, FIN-80101 Joensuu, Finland

来源：

INORGANIC CHEMISTRY | 2010年 / 49卷 / 14期

关键词：

IMPORTANT ZWITTERIONIC BUFFERS; HYDROGEN-ION BUFFERS; CATALYTIC FUNCTIONALIZATION; PEROXIDATIVE OXIDATION; TERNARY COMPLEXES; CARBOXYLIC-ACIDS; METAL-FREE; TRIETHANOLAMINE; ACTIVATION; EFFICIENT;

D O I：

10.1021/ic1007999

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

New water-soluble 1D and 3D Cu-II/Na coordination polymers 1-3 bearing unprecedented [Cu-4(Hbes)(4)] cores have been easily generated by aqueous-medium self-assembly and fully characterized, thus opening up the use of the common biological buffer H(3)bes, (HO3SCH2CH2)N(CH2CH2OH)(2), in synthetic coordination chemistry. Apart from representing the first isolated and structurally characterized coordination compounds derived from H(3)bes, 1-3 show a remarkable promoting effect in the mild aqueous-medium hydrocarboxylation, by CO and H2O, of gaseous alkanes (C3H8 and n-C4H10) to the corresponding carboxylic acids, which are obtained in up to 95% yields based on the alkane.

引用

页码：6390 / 6392

页数：3

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