The selective functionalization of saturated hydrocarbons. Part 43. Modified Gif oxidation in acetonitrile

被引：21

作者：

Barton, DHR ^{[1
]}

Li, TS ^{[1
]}

机构：

[1] Texas A&M Univ, Dept Chem, College Stn, TX 77843 USA

来源：

TETRAHEDRON | 1998年 / 54卷 / 09期

关键词：

D O I：

10.1016/S0040-4020(97)10398-2

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The role of pyridine and of many substituted pyridines in Gif oxidation chemistry has been examined. In the presence of a suitable pyridine type base most of the solvent can be replaced by acetonitrile without diminishing the yield of oxidation products. The use of 4-tert-butylpyridine permits the isolation of cyclohexanone and cyclohexanol by simple distillation. (C) 1998 Elsevier Science Ltd. All rights reserved.

引用

页码：1735 / 1744

页数：10

共 24 条

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Barton, DHR
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Barton, DHR
Hu, B
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[7] The importance of pyridine complexation on selective oxidation within the Fe(III)-Fe(V) manifold in Gif chemistry.
Barton, DHR
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[8] THE SELECTIVE FUNCTIONALIZATION OF SATURATED-HYDROCARBONS - GIF CHEMISTRY
BARTON, DHR
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[10] Hill C. L., 1989, ACTIVATION FUNCTIONA

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