Efficient and Convenient Oxidation of Organic Halides to Aldehydes and Ketones Catalyzed by H5IO6/V2O5 in Ionic Liquid [bmpy][PF6]

被引：9

作者：

Hu, Yu-Lin ^{[1
]}

Liu, Xiang ^{[1
]}

Lu, Ming ^{[1
]}

Jiang, Hui ^{[1
]}

机构：

[1] Nanjing Univ Sci & Technol, Chem Engn Coll, Nanjing 210094, Peoples R China

来源：

JOURNAL OF THE CHINESE CHEMICAL SOCIETY | 2010年 / 57卷 / 01期

关键词：

Oxidation; Organic halide; H5IO6/V2O5; Ionic liquid; CARBONYL-COMPOUNDS; BENZYL HALIDES; ALKYL-HALIDES; N-OXIDE; CONVERSION; ALCOHOLS; REAGENT;

D O I：

10.1002/jccs.201000005

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A mild, efficient, and eco-friendly procedure for the oxidation of organic halides to aldehydes and ketones in good to high yields catalyzed by H5IO6/V2O5 in ionic liquid [bmpy][PF6] with no trace of overoxidation to carboxylic acids has been developed. The product can be isolated by a simple extraction with organic solvent, and the catalytic system can be recycled or reused without any significant loss of catalytic activity.

引用

页码：28 / 33

页数：6

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