Structure of Sodium Borosilicate Glasses: Models and Experiment

被引：1

作者：

Osipov, A. A. ^{[1
]}

Osipova, L. M. ^{[1
]}

机构：

[1] Russian Acad Sci, South Ural Fed Sci Ctr Mineral & Geoecol, Ural Branch, Miass 456317, Russia

来源：

GLASS PHYSICS AND CHEMISTRY | 2022年 / 48卷 / 06期

关键词：

borosilicate glasses; Dell model; thermodynamic model; basic structural units; superstructural groupings; ALKALI SILICATE-GLASSES; RAMAN-SPECTROSCOPY; MAGMATIC TEMPERATURES; Q(N) DISTRIBUTION; MELTS; BORON; B-11; COORDINATION;

D O I：

10.1134/S1087659622600521

中图分类号：

TQ174 [陶瓷工业]; TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

This study is aimed at the analysis of two structural models of the structure of sodium borosilicate glasses (the Dell model and the thermodynamic (TD) model), which differ significantly in their fundamental principles. Where it is possible, we compare the model's predictions regarding the structural features of glasses in the Na2O-B2O3-SiO2 system on the near (distribution of basic structural units) and average (the content of superstructural groups as a function of glass composition) scales with the experimental data. The analysis gives an idea of the information content of both models and their correctness in terms of their predictions.

引用

页码：519 / 536

页数：18

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