Two novel two-dimensional frameworks with channels built from hydrogen bonds: Structures and properties study on copper(II) and nickel(II) complexes of the macrocyclic ligand 1,4,7-triazacyclodecane (tacd)

被引：2

作者：

Guo, Hui ^{[1
]}

Li, Jun ^{[1
]}

Ren, Yan-Wei ^{[1
]}

Liu, Jing-Jing ^{[1
]}

Zhang, Feng-Xing ^{[1
]}

机构：

[1] NW Univ Xian, Dept Chem, Shaanxi Key Lab Physicoinorgan Chem, Xian 710069, Peoples R China

来源：

JOURNAL OF CHEMICAL CRYSTALLOGRAPHY | 2007年 / 37卷 / 04期

基金：

中国国家自然科学基金;

关键词：

supramolecular complex; channel; two-dimensional framework; hydrogen bonds; copper(II) complex; nickel(II) complex; 1,4,7-triazacyclodecane;

D O I：

10.1007/s10870-006-9158-5

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

Two novel supramolecular complexes [Cu(tacd)(2)](C4H3O4)(2) (1) and [Ni(tacd)(2)]Cl-2 center dot 4H(2)O (2) were synthesized and their structures were characterized by elemental analysis, IR spectrum, TGA and single-crystal X-ray analysis. The results indicated that the complexes 1 and 2 assemble into different 2D supramolecular net-work structures with channels via hydrogen bonds interaction. TGA curves showed the steps of weight-loss for 1 and 2.

引用

页码：255 / 263

页数：9

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