Ionization energy of fullerenes

被引：92

作者：

Boltalina, OV ^{[1
]}

Ioffe, IN

Sidorov, LN

Seifert, G

Vietze, K

机构：

[1] Moscow State Univ, Dept Chem, Moscow 119899, Russia

[2] Univ Gesamthsch Paderborn, Fac Phys, D-33098 Paderborn, Germany

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2000年 / 122卷 / 40期

关键词：

D O I：

10.1021/ja000734b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Ionization energies of the higher fullerenes C-n (n = 70-106) were measured by means of the ion-molecular equilibria-Knudsen Cell mass spectrometry method. The obtained values were found to decrease with the size, going from LE(C-70) = 7.36 eV down to IE(C-105) = 6.92 eV, with unexpectedly low IE(C-74) 7.13 eV. A good correlation of the experimental results with the theoretical values is demonstrated. A simple model describing the ionization properties dependence from the fullerene size is proposed.

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页码：9745 / 9749

页数：5

相关论文

共 39 条

[1] ELECTRON-TRANSFER REACTIONS WITH BUCKMINSTERFULLERENE, C-60, IN THE GAS-PHASE [J].

BOHME, DK .

INTERNATIONAL REVIEWS IN PHYSICAL CHEMISTRY, 1994, 13 (02) :163-185

[2]

Boltalina OV, 1997, MASS SPECTROM REV, V16, P333, DOI 10.1002/(SICI)1098-2787(1997)16:6<333::AID-MAS2>3.0.CO

[3]

2-I

[4] Gibbs energies of gas-phase electron transfer reactions involving the larger fullerene anions [J].

Boltalina, OV ;

Dashkova, EV ;

Sidorov, LN .

CHEMICAL PHYSICS LETTERS, 1996, 256 (03) :253-260

[5] LASER PHOTODETACHMENT OF C-60(-) AND C-70(-) IONS COOLED IN A STORAGE-RING [J].

BRINK, C ;

ANDERSEN, LH ;

HVELPLUND, P ;

MATHUR, D ;

VOLDSTAD, JD .

CHEMICAL PHYSICS LETTERS, 1995, 233 (1-2) :52-56

[6] ELECTROSTATIC POTENTIAL, POLARIZATION, SHIELDING, AND CHARGE-TRANSFER IN ENDOHEDRAL COMPLEXES OF THE C-60, C-70, C-76, C-78, C-82, AND C-84 CLUSTERS [J].

CIOSLOWSKI, J ;

RAGHAVACHARI, K .

JOURNAL OF CHEMICAL PHYSICS, 1993, 98 (11) :8734-8741

[7] Electron attachment to a negative ion: e+C-84(-)reversible arrow C-84(-2) [J].

Compton, RN ;

Tuinman, AA ;

Klots, CE ;

Pederson, MR ;

Patton, DC .

PHYSICAL REVIEW LETTERS, 1997, 78 (23) :4367-4370

[8] SINGLE-PHOTON IONIZATION OF C-60-FULLERENE AND C-70-FULLERENE WITH SYNCHROTRON RADIATION - DETERMINATION OF THE IONIZATION-POTENTIAL OF C-60 [J].

DEVRIES, J ;

STEGER, H ;

KAMKE, B ;

MENZEL, C ;

WEISSER, B ;

KAMKE, W ;

HERTEL, IV .

CHEMICAL PHYSICS LETTERS, 1992, 188 (3-4) :159-162

[9] Isolation and properties of small-bandgap fullerenes [J].

Diener, MD ;

Alford, JM .

NATURE, 1998, 393 (6686) :668-671

[10] Energetics of C-20 and C-22 fullerene and near-fullerene carbon cages [J].

Domene, MC ;

Fowler, PW ;

Mitchell, D ;

Seifert, G ;

Zerbetto, F .

JOURNAL OF PHYSICAL CHEMISTRY A, 1997, 101 (44) :8339-8344

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