Synthesis and isomerization of 3-pyrroline enamines

被引：41

作者：

Cook, AG ^{[1
]}

Switek, KA ^{[1
]}

Cutler, KA ^{[1
]}

Witt, AN ^{[1
]}

机构：

[1] Valparaiso Univ, Dept Chem, Valparaiso, IN 46383 USA

来源：

LETTERS IN ORGANIC CHEMISTRY | 2004年 / 1卷 / 01期

关键词：

enamine; pyrrole; isomerization; pyrroline;

D O I：

10.2174/1570178043488734

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

`3-Pyrroline reacts with cyclic ketones to form enamines as kinetically controlled products. Under more vigorous conditions, pyrolles are formed as thermodynamically controlled products by way of a 1.3-hydride shift.

引用

页码：1 / 5

页数：5

共 8 条

[1] CATALYTIC DEHYDROGENATION OF HYDROAROMATIC COMPOUNDS IN BENZENE .5. APPLICATION TO PYRROLIDINES AND PIPERIDINES
ADKINS, H
LUNDSTED, LG
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1949, 71 (09) : 2964 - 2965
[2] COOK AG, 1988, SYNTHESIS STRUCTURE, pCH1
[3] PHOTOCHEMICAL STUDY .3. PHOTOCHEMISTRY OF THIOPHENE
COUTURE, A
LABLACHE.A
[J]. TETRAHEDRON, 1971, 27 (05) : 1059 - &
[4] GUROWITZ WD, 1965, TETRAHEDRON LETT, P4433
[5] PYRROLE STUDIES .12. AROMATIC CHARACTER OF 1-SUBSTITUTED PYRROLES
JONES, RA
SPOTSWOO.TM
CHEUYCHI.P
[J]. TETRAHEDRON, 1967, 23 (11) : 4469 - +
[6] HOMOALLYLIC INTERACTION BETWEEN NITROGEN LONE PAIR AND NONADJACENT PI-BOND IN CYCLIC AND BICYCLIC AMINES .1. PHOTOELECTRON SPECTROSCOPIC STUDY
MORISHIMA, I
YOSHIKAWA, K
HASHIMOTO, M
BEKKI, K
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1975, 97 (15) : 4283 - 4288
[7] MURCHASHI SI, 1974, J CHEM SOC CHEM COMM, P931
[8] Pretsch E., 1989, TABLES SPECTRAL DATA

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