Conversion of CO2 from air into formate using amines and phosphorus-nitrogen PN3P-Ru(ii) pincer complexes

被引：64

作者：

Guan, Chao ^{[1
]}

Pan, Yupeng ^{[1
]}

Ang, Eleanor Pei Ling ^{[1
]}

Hu, Jinsong ^{[1
]}

Yao, Changguang ^{[1
]}

Huang, Mei-Hui ^{[1
]}

Li, Huaifeng ^{[1
]}

Lai, Zhiping ^{[1
]}

Huang, Kuo-Wei ^{[1
]}

机构：

[1] KAUST, Div Phys Sci & Engn PSE, Thuwal 239556900, Saudi Arabia

来源：

GREEN CHEMISTRY | 2018年 / 20卷 / 18期

关键词：

RUTHENIUM-CATALYZED HYDROGENATION; CARBON-DIOXIDE; FORMIC-ACID; PN3-PINCER LIGAND; ROOM-TEMPERATURE; METHANOL; BICARBONATES; REDUCTION; PRESSURE; SYSTEMS;

D O I：

10.1039/c8gc02186d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Well-defined ruthenium(ii) (PNP)-P-3 pincer complexes were developed for the hydrogenation of carbon dioxide. Excellent product selectivity and catalytic activity with TOF (turnover frequency) and TON (turnover number) up to 13000 h(-1) and 33000, respectively, in a THF/H2O biphasic system were achieved. Notably, effective conversion of carbon dioxide from air into formate was conducted in the presence of an amine, allowing easy product separation and catalyst recycling.

引用

页码：4201 / 4205

页数：5

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