Aerobic Oxynitration of Alkynes with tBuONO and TEMPO

被引：107

作者：

Dutta, Uttarn ^{[1
]}

Maity, Soham ^{[1
]}

Kancherla, Rajesh ^{[1
]}

Maiti, Debabrata ^{[1
]}

机构：

[1] Indian Inst Technol, Dept Chem, Bombay 400076, Maharashtra, India

来源：

ORGANIC LETTERS | 2014年 / 16卷 / 24期

关键词：

TERMINAL ALKYNES; STEREOSELECTIVE NITRATION; EFFICIENT; OLEFINS; PHOTOREDOX; CATALYSIS; KETONES; VINYL; VINYLPHOSPHONATE; ACTIVATION;

D O I：

10.1021/ol503025n

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

An efficient method for stereoselective nitroaminoxylation of alkyne has been reported. The reaction enjoys a broad substrate scope, good functional group tolerance, and high yields. Synthetically useful a-nitroketones can be accessed through these products in a single step.

引用

页码：6302 / 6305

页数：4

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