Aerobic Oxynitration of Alkynes with tBuONO and TEMPO

被引：106
作者：
Dutta, Uttarn [1 ]
Maity, Soham [1 ]
Kancherla, Rajesh [1 ]
Maiti, Debabrata [1 ]
机构：
[1] Indian Inst Technol, Dept Chem, Bombay 400076, Maharashtra, India
来源：
ORGANIC LETTERS | 2014年 / 16卷 / 24期
关键词：
TERMINAL ALKYNES; STEREOSELECTIVE NITRATION; EFFICIENT; OLEFINS; PHOTOREDOX; CATALYSIS; KETONES; VINYL; VINYLPHOSPHONATE; ACTIVATION;
D O I：
10.1021/ol503025n
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
An efficient method for stereoselective nitroaminoxylation of alkyne has been reported. The reaction enjoys a broad substrate scope, good functional group tolerance, and high yields. Synthetically useful a-nitroketones can be accessed through these products in a single step.
引用
收藏
页码：6302 / 6305
页数：4
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