Electron dynamics in H2+ molecule-ion under a strong, oscillating magnetic field

被引:3
作者
Goel, N. [1 ,2 ]
Gupta, S. [3 ]
Sadhukhan, M. [4 ]
Deb, B. M. [5 ]
机构
[1] Panjab Univ, Dept Chem, Chandigarh, India
[2] Panjab Univ, Ctr Adv Studies Chem, Chandigarh, India
[3] Panjab Univ, Univ Inst Engn & Technol, Chandigarh, India
[4] Indian Inst Technol, Dept Chem, Kanpur, Uttar Pradesh, India
[5] Visva Bharati Univ, Publishing Dept, 6 AJC Bose Rd, Kolkata 700017, India
关键词
Magneto-optical and electro-optical effects; time-dependent phenomena; excitation and relaxation processes; and reaction rates; properties of molecules; HYDROGEN MOLECULE; GROUND-STATE; DENSITY; LASER; ATOM; MANIFOLD; BOND;
D O I
10.1080/00268976.2019.1676930
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
In this work, the dynamics of electronic motion in molecule-ion under an ultrafast, strong, oscillating magnetic field have been studied and compared with those from our earlier work on the H atom. Compared to the H atom, the presence of an additional electron-nuclear attraction and a nuclear-nuclear repulsion term in the molecular Hamiltonian make the two sets of dynamics somewhat different. In particular, the effective potential is not the same; there is now no slow dynamics; and, the photoemission spectrum shows both odd and even harmonics of the incident magnetic-field frequency. However, like the H atom, the possibility of coherent ultrafast photoemission remains.
引用
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页数:7
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