Physicochemical Investigations of Carbon Nanofiber Supported Cu/ZrO2 Catalyst

被引:10
作者
Din, Israf Ud [1 ]
Shaharun, Maizatul S. [1 ]
Subbarao, Duvvuri [2 ]
Naeem, A. [3 ]
机构
[1] Univ Teknol PETRONAS, Dept Fundamental & Appl Sci, Tronoh, Perak, Malaysia
[2] Univ Teknol PETRONAS, Dept Chem Engn, Perak, Malaysia
[3] Univ Peshawar, Natl Ctr Excellence Phys Chem, Peshawar, Pakistan
来源
3RD INTERNATIONAL CONFERENCE ON FUNDAMENTAL AND APPLIED SCIENCES (ICFAS 2014): INNOVATIVE RESEARCH IN APPLIED SCIENCES FOR A SUSTAINABLE FUTURE | 2014年 / 1621卷
关键词
DEPOSITION-PRECIPITATION; NI(II) PHASE; METHANOL SYNTHESIS; NICKEL PARTICLES; MECHANISM; NANOTUBES; OXIDATION; BEHAVIOR; KINETICS; SILICA;
D O I
10.1063/1.4898520
中图分类号
O59 [应用物理学];
学科分类号
摘要
Zirconia-promoted copper/carbon nanofiber catalysts (Cu-ZrO2/CNF) were prepared by the sequential deposition precipitation method. The Herringbone type of carbon nanofiber GNF-100 (Graphite nanofiber) was used as a catalyst support. Carbon nanofiber was oxidized to (CNF-O) with 5% and 65 % concentration of nitric acid (HNO3). The CNF activated with 5% HNO3 produced higher surface area which is 155 m(2)/g. The catalyst was characterized by X-ray Diffraction (XRD), Fourier Transform Infra-Red (FTIR) and N-2 adsorption-desorption. The results showed that increase of HNO3 concentration reduced the surface area and porosity of the catalyst.
引用
收藏
页码:549 / 554
页数:6
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