Metal organic framework MIL-101 for radioiodine capture and storage

被引：43

作者：

Assaad, Thaer ^{[1
]}

Assfour, Bassem ^{[2
]}

机构：

[1] AECS, Dept Radioisotope, POB 6091, Damascus, Syria

[2] AECS, Dept Chem, POB 6091, Damascus, Syria

来源：

JOURNAL OF NUCLEAR MATERIALS | 2017年 / 493卷

关键词：

Radioisotopes; Adsorption; Metal organic framework; SEM; EDX; XPS; IODINE; SORPTION;

D O I：

10.1016/j.jnucmat.2017.05.036

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

we report on the use of metal organic frameworks(MOFs) for radioiodine recovery and storage. One MOF (namely MIL-101) was prepared and investigated in detail to demonstrate the iodine removal efficiency and capacity of MOFs. The typical sorption kinetics and uptake isotherms were measured using radioactive iodine ((123) I) for the first time. Our measurements indicate that MOFs can capture and store radioiodine in very high efficiency and fast kinetics. (C) 2017 Elsevier B.V. All rights reserved.

引用

收藏

页码：6 / 11

页数：6

相关论文

共 15 条

[1] In silico screening of metal organic framework for iodine capture and storage [J].

Assfour, Bassem ;

Assaad, Thaer ;

Odeh, Adnan .

CHEMICAL PHYSICS LETTERS, 2014, 610 :45-49

[2] Capture of iodine in highly stable metal-organic frameworks: a systematic study [J].

Falaise, Clement ;

Volkringer, Christophe ;

Facqueur, Jacques ;

Bousquet, Till ;

Gasnot, Laurent ;

Loiseau, Thierry .

CHEMICAL COMMUNICATIONS, 2013, 49 (87) :10320-10322

[3] A chromium terephthalate-based solid with unusually large pore volumes and surface area [J].

Férey, G ;

Mellot-Draznieks, C ;

Serre, C ;

Millange, F ;

Dutour, J ;

Surblé, S ;

Margiolaki, I .

SCIENCE, 2005, 309 (5743) :2040-2042

[4] Metal-organic frameworks as efficient materials for drug delivery [J].

Horcajada, Patricia ;

Serre, Christian ;

Vallet-Regi, Maria ;

Sebban, Muriel ;

Taulelle, Francis ;

Ferey, Gerard .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2006, 45 (36) :5974-5978

[5] Thermochemical Evidence for Strong Iodine Chemisorption by ZIF-8 [J].

Hughes, James T. ;

Sava, Dorina F. ;

Nenoff, Tina M. ;

Navrotsky, Alexandra .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2013, 135 (44) :16256-16259

[6] MOFs, MILs and more: concepts, properties and applications for porous coordination networks (PCNs) [J].

Janiak, Christoph ;

Vieth, Jana K. .

NEW JOURNAL OF CHEMISTRY, 2010, 34 (11) :2366-2388

[7] Microwave synthesis of chromium terephthalate MIL-101 and its benzene sorption ability [J].

Jhung, Sung Hwa ;

Lee, Jin-Ho ;

Yoon, Ji Woong ;

Serre, Christian ;

Ferey, Gerard ;

Chang, Jong-San .

ADVANCED MATERIALS, 2007, 19 (01) :121-+

[8] Metal-organic framework materials as catalysts [J].

Lee, JeongYong ;

Farha, Omar K. ;

Roberts, John ;

Scheidt, Karl A. ;

Nguyen, SonBinh T. ;

Hupp, Joseph T. .

CHEMICAL SOCIETY REVIEWS, 2009, 38 (05) :1450-1459

[9] A Two-Column Method for the Separation of Kr and Xe from Process Off-Gases [J].

Liu, Jian ;

Fernandez, Carlos A. ;

Martin, Paul F. ;

Thallapally, Praveen K. ;

Strachan, Denis M. .

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2014, 53 (32) :12893-12899

[10] Capture and immobilisation of iodine (I2) utilising polymer-based ZIF-8 nanocomposite membranes [J].

Mahdi, E. M. ;

Chaudhuri, Abhijeet K. ;

Tan, Jin-Chong .

MOLECULAR SYSTEMS DESIGN & ENGINEERING, 2016, 1 (01) :122-131