Origin of the effect of ion nature on the differential capacity of an interface between two immiscible electrolyte solutions

被引：18

作者：

Samec, Z ^{[1
]}

Trojanek, A ^{[1
]}

Langmaier, J ^{[1
]}

机构：

[1] Acad Sci Czech Republ, J Heyrovsky Inst Phys Chem & Electrochem, CR-18223 Prague 8, Czech Republic

来源：

JOURNAL OF ELECTROANALYTICAL CHEMISTRY | 1998年 / 444卷 / 01期

关键词：

immiscible electrolyte solutions; capacity; capillary waves;

D O I：

10.1016/S0022-0728(97)00590-1

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

It is shown that the experimentally observed effect of ion nature on the capacity of the interface between two immiscible electrolyte solutions can be linked to periodic mechano-electric perturbations of the interfacial region during the ac impedance measurements rather than to the specific ion adsorption. (C) 1998 Elsevier Science S.A. All rights reserved.

引用

页码：1 / 5

页数：5

共 10 条

[1] Effect of the specific ion adsorption on the impedance of an interface between two immiscible electrolyte solutions
Samec, Z
JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1997, 426 (1-2) : 31 - 35
[2] Peculiar correlation between the interfacial capacity and faradaic admittance of the ion transfer across an interface between two immiscible electrolyte solutions
Samec, Z
Lhotsky, A
Marecek, V
ELECTROCHIMICA ACTA, 1999, 45 (4-5) : 583 - 590
[3] Ion amperometry at the interface between two immiscible electrolyte solutions in view of realizing the amperometric ion-selective electrode
Samec, Z
Samcová, E
Girault, HH
TALANTA, 2004, 63 (01) : 21 - 32
[4] Simple kinetic models of ion transfer across an interface between two immiscible electrolyte solutions. A comparison with experimental data
Samec, Z
ELECTROCHIMICA ACTA, 1998, 44 (01) : 85 - 90
[5] THE DOUBLE-LAYER AT THE INTERFACE BETWEEN 2 IMMISCIBLE ELECTROLYTE-SOLUTIONS .4. SOLVENT EFFECT
WANDLOWSKI, T
HOLUB, K
MARECEK, V
SAMEC, Z
ELECTROCHIMICA ACTA, 1995, 40 (18) : 2887 - 2895
[6] Interfacial tension and impedance measurements of interfaces between two immiscible electrolyte solutions
Samec, Z
Lhotsky, A
Jänchenová, H
Marecek, V
JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 2000, 483 (1-2) : 47 - 56
[7] A 4-ELECTRODE MICROCELL FOR ELECTROCHEMICAL MEASUREMENTS AT THE INTERFACE BETWEEN 2 IMMISCIBLE ELECTROLYTE-SOLUTIONS
SAMEC, Z
TROJANEK, A
SAMCOVA, E
JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1995, 386 (1-2) : 225 - 228
[8] Effect of capillary waves on the double layer capacitance of the interface between two immiscible electrolytes
Daikhin, LI
Kornyshev, AA
Urbakh, M
ELECTROCHIMICA ACTA, 1999, 45 (4-5) : 685 - 690
[9] Anomalous temperature dependence of differential capacity at an uncharged interface with Debye-Huckel electrolyte: Field theoretical approach
di Caprio, D
Stafiej, J
Borkowska, Z
JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 2005, 582 (1-2): : 41 - 49
[10] Limited agreement between the interfacial tension and differential capacity data for the polarised water|1,2-dichloroethane interface
Trojánek, A
Lhotsky, A
Marecek, V
Samec, Z
JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 2004, 565 (02) : 243 - 250

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