Agricultural waste-derived activated carbon for high performance lithium-ion capacitors

被引:44
作者
Li, Bing [1 ,2 ]
Zhang, Hongyou [1 ,2 ]
Wang, Dabin [1 ,2 ]
Lv, Hong [1 ,2 ]
Zhang, Cunman [1 ,2 ]
机构
[1] Tongji Univ, Clean Energy Automot Engn Ctr, Shanghai 201804, Peoples R China
[2] Tongji Univ, Sch Automot Studies, Shanghai 201804, Peoples R China
关键词
HYBRID SUPERCAPACITORS; ELECTROCHEMICAL CAPACITORS; HIGH-ENERGY; POROUS CARBON; ELECTRODES; GRAPHENE; DENSITY; CATHODE; BIOMASS; STORAGE;
D O I
10.1039/c7ra06680e
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Activated carbon (AC) derived from the most common agricultural waste, corncob, has been synthesized through a simple chemical activation process. Furthermore, high energy density lithium-ion capacitors (LICs) were fabricated using corncob-derived AC as the cathode and commercially available Li4Ti5O12 as the anode. The optimized LIC achieves a maximum energy density of 79.6 W h kg(-1) and is also capable of delivering high power density of 4 kW kg(-1), which is much higher than that of similar constructions employing commercial AC as the cathode. In addition, the corncob-based LIC exhibits great cycle performance with 85.2% retention of the initial capacitance value after 2000 cycles. The present research offers a new approach for the development of high performance LICs employing carbonaceous electrodes of biomass precursors. These results make the corncob-derived activated carbon the most promising candidate for future energy storage applications.
引用
收藏
页码:37923 / 37928
页数:6
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