Solvation thermodynamics in a van der Waals liquid

被引：11
作者：
Graziano, G [1 ]
机构：
[1] Univ Naples Federico II, Dipartimento Chim, I-80126 Naples, Italy
来源：
THERMOCHIMICA ACTA | 2003年 / 399卷 / 1-2期
关键词：
solvation; chemical potential; Ben-Naim standard; van der Waals model;
D O I：
10.1016/S0040-6031(02)00457-4
中图分类号：
O414.1 [热力学];
学科分类号：
摘要：
The expression of the chemical potential of a solute in a solvent is derived exploiting the van der Waals model of liquids using a statistical thermodynamical approach. Then the solvation thermodynamics is determined, and discussed in detail for the case of an infinitely dilute solution. The analysis shows that the definitions introduced by Ben-Naim are exact and need no corrections. Moreover, the results obtained are in line with the theoretical approach devised by Lee to rationalize the experimental thermodynamic data of solvation. (C) 2002 Elsevier Science B.V. All rights reserved.
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收藏
页码：181 / 187
页数：7
相关论文
共 55 条
[1]  
[Anonymous], 1890, Z PHYS CHEM
[2]   Size dependence of solvation Gibbs energies: A critique and a rebuttal of some recent publications [J].
Ben-Naim, A ;
Mazo, R .
JOURNAL OF PHYSICAL CHEMISTRY B, 1997, 101 (51) :11221-11225
[3]  
Ben-Naim A., 1987, SOLVATION THERMODYNA
[4]  
Ben-Naim A., 1974, Water and Aqueous Solutions, Introduction to Molecular Theory
[5]   SOLVATION OF LARGE MOLECULES - SOME EXACT RESULTS ON THE DEPENDENCE ON VOLUME AND SURFACE-AREA OF THE SOLUTE [J].
BENNAIM, A .
BIOPHYSICAL CHEMISTRY, 1994, 51 (2-3) :203-216
[6]   SOLVATION THERMODYNAMICS OF NONIONIC SOLUTES [J].
BENNAIM, A ;
MARCUS, Y .
JOURNAL OF CHEMICAL PHYSICS, 1984, 81 (04) :2016-2027
[7]   STANDARD THERMODYNAMICS OF TRANSFER - USES AND MISUSES [J].
BENNAIM, A .
JOURNAL OF PHYSICAL CHEMISTRY, 1978, 82 (07) :792-803
[8]   SIZE DEPENDENCE OF THE SOLVATION FREE-ENERGIES OF LARGE SOLUTES [J].
BENNAIM, A ;
MAZO, RM .
JOURNAL OF PHYSICAL CHEMISTRY, 1993, 97 (41) :10829-10834
[9]  
BLOKZIJL W, 1993, ANGEW CHEM INT EDIT, V32, P1545, DOI 10.1002/anie.199315451
[10]   Solvation: How to obtain microscopic energies from partitioning and solvation experiments [J].
Chan, HS ;
Dill, KA .
ANNUAL REVIEW OF BIOPHYSICS AND BIOMOLECULAR STRUCTURE, 1997, 26 :425-459
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