Effect of high pressure on the kinetics and mechanism of thermolysis of organic peroxides in solution

被引：1

作者：

Antonovskii, VL ^{[1
]}

Zhulin, VM

机构：

[1] Russian Acad Sci, NN Semenov Chem Phys Inst, Moscow 119991, Russia

[2] Russian Acad Sci, Zelinskii Inst Organ Chem, Moscow 119992, Russia

来源：

KINETICS AND CATALYSIS | 2003年 / 44卷 / 01期

关键词：

D O I：

10.1023/A:1022520717880

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

This review analyzes published data and experimental results obtained by the authors concerning the effect of high pressure on the chemical kinetics of thermal decomposition of the main types of organic and organosilicon peroxides in solution. The volume effect of activation was found to depend on the mechanism of peroxide decomposition and on the properties of solvents.

引用

页码：74 / 81

页数：8

共 50 条

[31] CONTROLLED DEGRADATION OF POLYPROPYLENE IN SOLUTION BY ORGANIC PEROXIDES [J].

COUTINHO, FMB ;

COSTA, THS .

POLYMER TESTING, 1994, 13 (04) :363-366

[32] ASYMMETRICAL BIFUNCTIONAL ORGANIC PEROXIDES AS INITIATORS FOR THE HIGH-PRESSURE POLYMERIZATION OF ETHYLENE [J].

LUFT, G ;

DORN, M .

JOURNAL OF MACROMOLECULAR SCIENCE-CHEMISTRY, 1988, A25 (08) :987-998

[33] KINETIC EFFECTS OF HIGH-PRESSURE AND THE MECHANISM OF THERMAL TRANSFORMATIONS OF ORGANOSILICON PEROXIDES [J].

ZHULIN, VM ;

RUDAKOV, OB ;

STASHINA, GA ;

GANYUSHKIN, AV ;

YABLOKOV, VA ;

VAINBERG, NN .

BULLETIN OF THE ACADEMY OF SCIENCES OF THE USSR DIVISION OF CHEMICAL SCIENCE, 1985, 34 (09) :1825-1833

[34] INTERACTION KINETICS OF PEROXIDES AND ORGANIC SULFIDES IN ATACTIC POLYPROPYLENE [J].

SHLYAPNIKOV, YA ;

KOLESNIKOVA, NN .

EUROPEAN POLYMER JOURNAL, 1987, 23 (08) :633-637

[35] Mono, Di and Trifunctional Cyclic Organic Peroxides: The Effect of Substituents and Ring Size on their Thermolysis in 1,4-dioxan [J].

Nesprias, Rosa ;

Eyler, Gladys ;

Canizo, Adriana .

AUSTRALIAN JOURNAL OF CHEMISTRY, 2013, 66 (09) :1080-1087

[36] Simulation of Chemical Kinetics of Elastomer Crosslinking by Organic Peroxides [J].

Likozar, Blaz ;

Krajnc, Matjaz .

POLYMER ENGINEERING AND SCIENCE, 2009, 49 (01) :60-72

[37] EXPERIMENTAL-DATA ON THE THERMAL KINETICS OF ORGANIC PEROXIDES [J].

HORDIJK, AC ;

DEGROOT, JJ .

THERMOCHIMICA ACTA, 1986, 101 :45-63

[38] ORGANIC PEROXIDES .20. PREPARATIVE DECARBOXYLATION OF CARBOXYLIC-ACIDS BY PERESTER THERMOLYSIS [J].

LANGHALS, H ;

RUCHARDT, C .

CHEMISCHE BERICHTE-RECUEIL, 1975, 108 (06) :2156-2158

[39] KINETICS AND MECHANISM OF THERMOLYSIS OF PROPIONE ALDOXIME AND ACETONE OXIME [J].

GEISELER, G ;

STOCK, S ;

SCHERZER, K .

ZEITSCHRIFT FUR PHYSIKALISCHE CHEMIE-LEIPZIG, 1971, 248 (3-4) :193-&

[40] THE KINETICS AND MECHANISM OF THERMOLYSIS OF POLY(ALKYLENE TEREPHTHALATE)S [J].

RAFLER, G ;

BLAESCHE, J ;

MOLLER, B ;

STROMEYER, M .

ACTA POLYMERICA, 1981, 32 (10) :608-611

← 1 2 3 4 5 →