Dielectric and microwave absorption properties of divalent-doped Na3Zr2Si2PO12 ceramics

被引:33
作者
Chen, Dan [1 ]
Luo, Fa [1 ]
Gao, Lu [1 ]
Zhou, Wancheng [1 ]
Zhu, Dongmei [1 ]
机构
[1] Northwestern Polytech Univ, State Key Lab Solidificat Proc, Xian 710072, Shaanxi, Peoples R China
关键词
Na3Zr2Si2PO12; Divalent doping; Dielectric; Microwave absorption; CONDUCTIVITY; PERFORMANCE; COMPOSITES; PHASE;
D O I
10.1016/j.jeurceramsoc.2018.05.039
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
The work attempted to develop a new kind of high temperature microwave absorption material. Dense Na3Zr1.9M0.1Si2PO11.9 (M = Ca2+, Ni2+, Mg2+, Co2+, Zn2+) and Na3Zr2-xZnxSi2PO12-x (x = 0.1, 0.2, 0.3, 0.4) ceramics were prepared by solid-state reactions for phase, microstructure characterization and dielectric properties, microwave absorption properties analysis. Results show that the complex permittivity increases in all the divalent-doped Na3Zr2Si2PO12 ceramics. Na3Zr1.8Zn0.2Si2PO11.8 ceramic exhibits the highest complex permittivity and optimum microwave absorption performance. The lowest reflection loss is -28.1 dB at 9.88 GHz and the bandwidth is 4.14 GHz (8.26-12.4 GHz) with a thickness of 2.1 mm. It indicates that Na3Zr2Si2PO12 ceramic can be chosen as a potential candidate of microwave absorption material and the performance can be enhanced by divalent doping strategy.
引用
收藏
页码:4440 / 4445
页数:6
相关论文
共 29 条
[1]  
[Anonymous], 2004, DIELECTRIC PHENOMENA
[2]   Influence of Nb5+, Ti4+, Y3+ and Zn2+ doped Na3Zr2Si2PO12 solid electrolyte on its conductivity [J].
Chen, Dan ;
Luo, Fa ;
Zhou, Wancheng ;
Zhu, Dongmei .
JOURNAL OF ALLOYS AND COMPOUNDS, 2018, 757 :348-355
[3]   Dielectric properties in the microwave range of Na3Zr2Si2PO12 ceramics [J].
Chen, Dan ;
Luo, Fa ;
Zhou, Wancheng ;
Zhu, Dongmei .
MATERIALS LETTERS, 2018, 221 :172-174
[4]   Influence of Indium-Tin Oxide Additive on the Sintering Process and Conductivity of Na3Zr2Si2PO12 Solid Electrolyte [J].
Chen, Dan ;
Luo, Fa ;
Gao, Lu ;
Zhou, Wancheng ;
Zhu, Dongmei .
JOURNAL OF ELECTRONIC MATERIALS, 2017, 46 (11) :6367-6372
[5]   Challenges and Perspectives for NASICON-Type Electrode Materials for Advanced Sodium-Ion Batteries [J].
Chen, Shuangqiang ;
Wu, Chao ;
Shen, Laifa ;
Zhu, Changbao ;
Huang, Yuanye ;
Xi, Kai ;
Maier, Joachim ;
Yu, Yan .
ADVANCED MATERIALS, 2017, 29 (48)
[6]   Formation of a Segregated Electrically Conductive Network Structure in a Low-Melt-Viscosity Polymer for Highly Efficient Electromagnetic Interference Shielding [J].
Cui, Cheng-Hua ;
Yan, Ding-Xiang ;
Pang, Huan ;
Xu, Xin ;
Jia, Li-Chuan ;
Li, Zhong-Ming .
ACS SUSTAINABLE CHEMISTRY & ENGINEERING, 2016, 4 (08) :4137-4145
[7]   Ion transport in sodium ion conducting solid electrolytes [J].
Fergus, Jeffrey W. .
SOLID STATE IONICS, 2012, 227 :102-112
[8]   Survey of the transport properties of sodium superionic conductor materials for use in sodium batteries [J].
Guin, M. ;
Tietz, F. .
JOURNAL OF POWER SOURCES, 2015, 273 :1056-1064
[9]   Improving the ionic conductivity of NASICON through aliovalent cation substitution of Na3Zr2Si2PO12 [J].
Jolley, Adam G. ;
Cohn, Gil ;
Hitz, Gregory T. ;
Wachsman, Eric D. .
IONICS, 2015, 21 (11) :3031-3038
[10]   Structural Investigation of Monoclinic-Rhombohedral Phase Transition in Na3Zr2Si2PO12 and Doped NASICON [J].
Jolley, Adam G. ;
Taylor, Daniel D. ;
Schreiber, Nathaniel J. ;
Wachsman, Eric D. .
JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 2015, 98 (09) :2902-2907