Dielectric and microwave absorption properties of divalent-doped Na3Zr2Si2PO12 ceramics

被引:32
作者
Chen, Dan [1 ]
Luo, Fa [1 ]
Gao, Lu [1 ]
Zhou, Wancheng [1 ]
Zhu, Dongmei [1 ]
机构
[1] Northwestern Polytech Univ, State Key Lab Solidificat Proc, Xian 710072, Shaanxi, Peoples R China
关键词
Na3Zr2Si2PO12; Divalent doping; Dielectric; Microwave absorption; CONDUCTIVITY; PERFORMANCE; COMPOSITES; PHASE;
D O I
10.1016/j.jeurceramsoc.2018.05.039
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
The work attempted to develop a new kind of high temperature microwave absorption material. Dense Na3Zr1.9M0.1Si2PO11.9 (M = Ca2+, Ni2+, Mg2+, Co2+, Zn2+) and Na3Zr2-xZnxSi2PO12-x (x = 0.1, 0.2, 0.3, 0.4) ceramics were prepared by solid-state reactions for phase, microstructure characterization and dielectric properties, microwave absorption properties analysis. Results show that the complex permittivity increases in all the divalent-doped Na3Zr2Si2PO12 ceramics. Na3Zr1.8Zn0.2Si2PO11.8 ceramic exhibits the highest complex permittivity and optimum microwave absorption performance. The lowest reflection loss is -28.1 dB at 9.88 GHz and the bandwidth is 4.14 GHz (8.26-12.4 GHz) with a thickness of 2.1 mm. It indicates that Na3Zr2Si2PO12 ceramic can be chosen as a potential candidate of microwave absorption material and the performance can be enhanced by divalent doping strategy.
引用
收藏
页码:4440 / 4445
页数:6
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