Allosteric silver(I) ion binding with peripheral π clefts of a Ce(IV) double decker porphyrin

被引：64
作者：
Ikeda, M [1 ]
Tanida, T [1 ]
Takeuchi, M [1 ]
Shinkai, S [1 ]
机构：
[1] Kyushu Univ, Grad Sch Engn, Dept Chem & Biochem, Fukuoka 8128581, Japan
来源：
ORGANIC LETTERS | 2000年 / 2卷 / 13期
关键词：
D O I：
10.1021/ol005807a
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A cerium(IV) double decker porphyrin (1) bearing four 4-methoxyphenyl groups was synthesized. Compound 1 shows a positive, homotoropic allosteric effect in metal recognition of Ag+ ion, and the peripheral pi clefts of 1 act as effective binding sites for Ag+ ion.
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页码：1803 / 1805
页数：3
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