XPS and XTEM study of A1N formation by N2+ implantation of aluminium

被引:38
作者
Osterle, W [1 ]
Dorfel, I
Urban, I
Reier, T
Schultze, JW
机构
[1] Bundesanstalt Mat Forsch & Prufung, D-12205 Berlin, Germany
[2] Univ Dusseldorf, Inst Phys Chem & Elektrochem, D-40225 Dusseldorf, Germany
关键词
AlN; aluminium; N-2(+) implantation; XPS; XTEM;
D O I
10.1016/S0257-8972(98)00355-7
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
X-ray photoelectron spectroscopy (XPS) and cross-sectional transmission electron microscopy (XTEM) were used to study the formation of AlN films by N-2(+) ion implantation of aluminium at energies of 3 keV and 100 keV. In both cases, a two-stage mechanism was found, comprising first the oriented precipitation of small particles of the hexagonal AlN-phase. followed by growth and coalescence finally forming a continuous AlN-layer while increasing the implantation dose from 1 x 10(17) cm(-2) to 2 x 10(17) cm(-2). The results of both methods are in excellent agreement and furthermore provide complementary information concerning chemical composition and binding energies as well as microstructural details. (C) 1998 Elsevier Science S.A.
引用
收藏
页码:168 / 174
页数:7
相关论文
共 14 条
[1]  
BRIGGS D, 1990, PRACTICAL SURFACE AN, V1, P601
[2]   NANOHARDNESS AND TRANSMISSION ELECTRON-MICROSCOPY STUDY OF NITROGEN-IMPLANTED ALUMINUM [J].
LUCAS, S ;
CHEVALLIER, J .
SURFACE & COATINGS TECHNOLOGY, 1994, 65 (1-3) :128-132
[3]  
LUCAS S, 1992, SURF COAT TECH, V51, pY441
[4]   SYNTHESIS OF ALUMINUM NITRIDE THIN-FILMS BY ION-VAPOR DEPOSITION METHOD [J].
NAKAMURA, Y ;
WATANABE, Y ;
HIRAYAMA, S ;
NAOTA, Y .
SURFACE & COATINGS TECHNOLOGY, 1994, 68 :203-207
[5]   Microstructural modifications of aluminium surfaces ion implanted with W and its effect on corrosion and passivation [J].
Rangel, CM ;
Travassos, MA ;
Chevallier, J .
SURFACE & COATINGS TECHNOLOGY, 1997, 89 (1-2) :101-107
[6]  
RINNER M, IN PRESS P ICAM 97 E
[7]   QUANTITATIVE-EVALUATION OF AES DEPTH PROFILES OF THIN ANODIC OXIDE-FILMS (TA2O5 TA, NB2O5 NB) [J].
SANZ, JM ;
HOFMANN, S .
SURFACE AND INTERFACE ANALYSIS, 1983, 5 (05) :210-216
[8]  
Serventi AM, 1996, MATER RES SOC SYMP P, V400, P287
[9]  
SIMSON S, 1996, SURF COAT TECH, V83, P287
[10]   SYNTHESIS AND STABILITY OF NITRIDE LAYERS IN IRON BY MEGAELECTRONVOLT NITROGEN IMPLANTATION [J].
VREDENBERG, AM ;
PEREZMARTIN, CM ;
CUSTER, JS ;
BOERMA, DO ;
DEWIT, L ;
SARIS, FW ;
VANDERPERS, NM ;
DEKEIJSER, TH ;
MITTEMEIJER, EJ .
SURFACE & COATINGS TECHNOLOGY, 1992, 51 (1-3) :79-86