Broad spectral sensitization of organic photovoltaic heterojunction device by perylene and C60

被引:35
作者
Feng, W
Fujii, A
Lee, S
Wu, H
Yoshino, K
机构
[1] Osaka Univ, Dept Elect Engn, Grad Sch Engn, Suita, Osaka 5650871, Japan
[2] Xian Jiao Tong Univ, Sch Elect & Informat Engn, Xian 710049, Peoples R China
关键词
D O I
10.1063/1.1323514
中图分类号
O59 [应用物理学];
学科分类号
摘要
The characteristics of heterojunction devices consisting of indium-tin-oxide (ITO)/poly(3-alkylthiophene) (PAT)/N,N-'-diphenyl glyoxaline-3, 4, 9, 10-perylene tetracarboxylic acid diacidamide (PV)/Al, ITO/PAT-PV/PV/Al, and ITO/PAT-PV-C-60/PV/Al, which are typical photoinduced rectifiers, are reported. The device under dark conditions is almost insulating; however, when exposed to light marked rectification and strong photoresponse over a broad spectral range covering near-infrared to visible and UV wavelengths are observed. The effect of PV and C-60 doping as well as annealing on spectral photoresponse and photoelectric conversion was investigated. The results show that the efficient photoinduced electron transfer from PAT to PV and C-60 occurs at the interface between the composite and junction. (C) 2000 American Institute of Physics. [S0021- 8979(00)04624-7].
引用
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页码:7120 / 7123
页数:4
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