Pushing the limits of sensitivity and resolution for natural abundance 43Ca NMR using ultra-high magnetic field (35.2 T)

被引：21

作者：

Bonhomme, Christian ^{[1
]}

Wang, Xiaoling ^{[2
]}

Hung, Ivan ^{[2
]}

Gan, Zhehong ^{[2
]}

Gervais, Christel ^{[1
]}

Sassoye, Capucine ^{[1
]}

Rimsza, Jessica ^{[3
]}

Du, Jincheng ^{[3
]}

Smith, Mark E. ^{[4
]}

Hanna, John V. ^{[5
]}

Sarda, Stephanie ^{[6
]}

Gras, Pierre ^{[7
]}

Combes, Christele ^{[7
]}

Laurencin, Danielle ^{[8
]}

机构：

[1] Sorbonne Univ, CNRS, Coll France, LCMCP, F-75005 Paris, France

[2] Natl High Magnet Field Lab, 1800 East Paul Dirac Dr, Tallahassee, FL 32310 USA

[3] Univ North Texas, Dept Mat Sci & Engn, Denton, TX 76207 USA

[4] Univ Lancaster, Dept Chem, Lancaster LA1 4YB, England

[5] Univ Warwick, Dept Phys, Coventry CV4 7AL, W Midlands, England

[6] Univ Paul Sabatier, Univ Toulouse, CIRIMAT, CNRS, 4 Allee E Monso, F-31030 Toulouse 4, France

[7] Univ Toulouse, CIRIMAT, CNRS, INPT Ensiacet, 4 Allee E Monso, F-31030 Toulouse 4, France

[8] CNRS UM ENSCM, ICGM, UMR 5253, Pl E Bataillon,CC1701, F-34095 Montpellier 05, France

来源：

CHEMICAL COMMUNICATIONS | 2018年 / 54卷 / 69期

基金：

英国工程与自然科学研究理事会;

关键词：

CALCIUM PYROPHOSPHATE DIHYDRATE; CRYSTAL-STRUCTURE; MAS NMR; SPECTROSCOPY; GLASSES; ENVIRONMENTS; SILICATE; SITES;

D O I：

10.1039/c8cc05193c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Natural abundance Ca-43 solid state NMR experiments are reported for the first time at ultra-high magnetic field (35.2 T) on a series of Ca-(pyro)phosphate and Ca-oxalate materials, which are of biological relevance in relation to biomineralization processes and the formation of pathological calcifications. The significant gain in both sensitivity and resolution at 35.2 T leads to unprecedented insight into the structure of both crystalline and amorphous phases.

引用

页码：9591 / 9594

页数：4

共 27 条

[1] Coexistence of amorphous and crystalline calcium carbonate in skeletal tissues
Aizenberg, J
Weiner, S
Addadi, L
[J]. CONNECTIVE TISSUE RESEARCH, 2003, 44 : 20 - 25
[2] Contribution of 43Ca MAS NMR for probing the structural configuration of calcium in glass
Angeli, Frederic
Gaillard, Marina
Jollivet, Patrick
Charpentier, Thibault
[J]. CHEMICAL PHYSICS LETTERS, 2007, 440 (4-6) : 324 - 328
[3] Structure of the β form of calcium pyrophosphate tetrahydrate
Balic-Zunic, T
Christoffersen, MR
Christoffersen, J
[J]. ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE CRYSTAL ENGINEERING AND MATERIALS, 2000, 56 : 953 - 958
[4] Calcium binding environments probed by 43Ca NMR spectroscopy
Bryce, David L.
[J]. DALTON TRANSACTIONS, 2010, 39 (37) : 8593 - 8602
[5] High sensitivity and resolution in 43Ca solid-state NMR experiments
Burgess, Kevin M. N.
Perras, Frederic A.
Moudrakovski, Igor L.
Xu, Yijue
Bryce, David L.
[J]. CANADIAN JOURNAL OF CHEMISTRY, 2015, 93 (08) : 799 - 807
[6] Calcium Carbonate Polyamorphism and Its Role in Biomineralization: How Many Amorphous Calcium Carbonates Are There?
Cartwright, Julyan H. E.
Checa, Antonio G.
Gale, Julian D.
Gebauer, Denis
Sainz-Diaz, C. Ignacio
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2012, 51 (48) : 11960 - 11970
[7] Probing Calcium-Based Metal-Organic Frameworks via Natural Abundance 43Ca Solid-State NMR Spectroscopy
Chen, Shoushun
Lucier, Bryan E. G.
Chen, Mansheng
Terskikh, Victor V.
Huang, Yining
[J]. CHEMISTRY-A EUROPEAN JOURNAL, 2018, 24 (35) : 8732 - 8736
[8] Whewellite, CaC2O4•H2O: structural study by a combined NMR, crystallography and modelling approach
Colas, Helene
Bonhomme-Coury, Laure
Diogo, Cristina Coelho
Tielens, Frederik
Babonneau, Florence
Gervais, Christel
Bazin, Dominique
Laurencin, Danielle
Smith, Mark E.
Hanna, John V.
Daudon, Michel
Bonhomme, Christian
[J]. CRYSTENGCOMM, 2013, 15 (43): : 8840 - 8847
[9] Calcium environment in silicate and aluminosilicate glasses probed by 43Ca MQMAS NMR experiments and MD-GIPAW calculations
Gambuzzi, Elisa
Pedone, Alfonso
Menziani, Maria Cristina
Angeli, Frederic
Florian, Pierre
Charpentier, Thibault
[J]. SOLID STATE NUCLEAR MAGNETIC RESONANCE, 2015, 68-69 : 31 - 36
[10] NMR spectroscopy up to 35.2 T using a series-connected hybrid magnet
Gan, Zhehong
Hung, Ivan
Wang, Xiaoling
Paulino, Joana
Wu, Gang
Litvak, Ilya M.
Gor'kov, Peter L.
Brey, William W.
Lendi, Pietro
Schiano, Jeffrey L.
Bird, Mark D.
Dixon, Lain R.
Toth, Jack
Boebinger, Gregory S.
Cross, Timothy A.
[J]. JOURNAL OF MAGNETIC RESONANCE, 2017, 284 : 125 - 136

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