Aqua(2,2′-diamino-4,4′-bi-1,3-thiazole-κ2N,N′)(oxydiacetato-κ3O,O′,O")cobalt(II) trihydrate

被引：0

作者：

Wu, Zhi-Yong ^{[1
]}

Sun, Wei ^{[1
]}

Li, Yan-Tuan ^{[1
]}

机构：

[1] Ocean Univ China, Marine Drug & Food Inst, Qingdao 266003, Peoples R China

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY | 2007年 / 63卷

关键词：

D O I：

10.1107/S0108270107011468

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The title compound, [Co(C4H4O5)(C6H6N4S2)(H2O)]center dot 3H(2)O, displays a distorted octahedral coordination geometry. The tridentate oxydiacetate dianion chelates the Cu-II atom in the meridional mode. In the crystal packing, hydrophilic and hydrophobic layers are arranged in an alternating manner. In addition, a three-dimensional hydrogen-bonding framework and pi-pi stacking are present.

引用

页码：M177 / M180

页数：4

共 24 条

[1] The Cambridge Structural Database: a quarter of a million crystal structures and rising [J].

Allen, FH .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 2002, 58 (3 PART 1) :380-388

[2]

[Anonymous], 1999, J. Appl. Crystallogr, DOI [DOI 10.1107/S0021889899006020, 10.1107/S0021889899006020]

[3] X-ray study on the nickel(II)-oxydiacetic system and its 1,10-phenanthroline and 2,2′:6′,2" terpyridine complexes [J].

Baggio, R ;

Garland, MT ;

Perec, M .

INORGANICA CHIMICA ACTA, 2000, 310 (01) :103-109

[4] Synthesis and characterization of zinc(II) oxydiacetate (oda) complexes. Crystal structures of [{Zn(oda)center dot 0.3H(2)O}(n)], [Zn(oda)(bipy)(H2O)]center dot 2.5H(2)O and [Zn(oda)(phen)(H2O)]center dot 1.5H(2)O (bipy=2,2'-bipyridine, phen=1,10-phenanthroline) [J].

Baggio, R ;

Garland, MT ;

Perec, M .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1996, (13) :2747-2753

[5]

*BRUK AXS INC, 2002, SAINT SMART

[6] GENERAL DEFINITION OF RING PUCKERING COORDINATES [J].

CREMER, D ;

POPLE, JA .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1975, 97 (06) :1354-1358

[7] THE PHOTOSYNTHETIC REACTION CENTER FROM THE PURPLE BACTERIUM RHODOPSEUDOMONAS-VIRIDIS [J].

DEISENHOFER, J ;

MICHEL, H .

EMBO JOURNAL, 1989, 8 (08) :2149-2170

[8] Synthesis and spectroscopic and x-ray structural characterization of R2SnIV-oxydiacetate and -iminodiacetate complexes [J].

Di Nicola, C ;

Galindo, A ;

Hanna, JV ;

Marchetti, F ;

Pettinari, C ;

Pettinari, R ;

Rivarola, E ;

Skelton, BW ;

White, AH .

INORGANIC CHEMISTRY, 2005, 44 (09) :3094-3102

[9] INTERACTION OF BLEOMYCIN A-2 WITH DEOXYRIBONUCLEIC-ACID - DNA UNWINDING AND INHIBITION OF BLEOMYCIN-INDUCED DNA BREAKAGE BY CATIONIC THIAZOLE AMIDES RELATED TO BLEOMYCIN A-2 [J].

FISHER, LM ;

KURODA, R ;

SAKAI, TT .

BIOCHEMISTRY, 1985, 24 (13) :3199-3207

[10] Manganese oxydiacetate complexes: Synthesis, structure and magnetic properties [J].

Grirrane, A ;

Pastor, A ;

Alvarez, E ;

Mealli, C ;

Ienco, A ;

Rosa, P ;

Montilla, F ;

Galindo, A .

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2004, (04) :707-717

← 1 2 3 →