Reaction chemistry in rechargeable Li-O2 batteries

被引:350
作者
Lim, Hee-Dae [1 ]
Lee, Byungju [1 ]
Bae, Youngjoon [1 ]
Park, Hyeokjun [1 ]
Ko, Youngmin [1 ]
Kim, Haegyeom [1 ]
Kim, Jinsoo [1 ]
Kang, Kisuk [1 ,2 ]
机构
[1] Seoul Natl Univ, RIAM, Dept Mat Sci & Engn, 1 Gwanak Ro, Seoul 151742, South Korea
[2] Seoul Natl Univ, Ctr Nanoparticle Res, IBS, 1 Gwanak Ro, Seoul 151742, South Korea
基金
新加坡国家研究基金会;
关键词
LITHIUM-OXYGEN BATTERY; TRANSMISSION ELECTRON-MICROSCOPY; HIERARCHICAL AIR ELECTRODE; CHARGE-TRANSPORT; DISCHARGE PRODUCT; SOLVENT STABILITY; KINETIC OVERPOTENTIALS; LI2O2; OXIDATION; O-2; REDUCTION; REDOX SHUTTLE;
D O I
10.1039/c6cs00929h
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The seemingly simple reaction of Li-O-2 batteries involving lithium and oxygen makes this chemistry attractive for high-energy-density storage systems; however, achieving this reaction in practical rechargeable Li-O-2 batteries has proven difficult. The reaction paths leading to the final Li2O2 discharge products can be greatly affected by the operating conditions or environment, which often results in major side reactions. Recent research findings have begun to reveal how the reaction paths may be affected by the surrounding conditions and to uncover the factors contributing to the difficulty in achieving the reactions of lithium and oxygen. This progress report describes the current state of understanding of the electrode reaction mechanisms in Li-O-2 batteries; the factors that affect reaction pathways; and the effect of cell components such as solvents, salts, additives, and catalysts on the discharge product and its decomposition during charging. This comprehensive review of the recent progress in understanding the reaction chemistry of the Li-O-2 system will serve as guidelines for future research and aid in the development of reliable high-energy-density rechargeable Li-O-2 batteries.
引用
收藏
页码:2873 / 2888
页数:16
相关论文
共 135 条
[1]   Current density dependence of peroxide formation in the Li-O2 battery and its effect on charge [J].
Adams, Brian D. ;
Radtke, Claudio ;
Black, Robert ;
Trudeau, Michel L. ;
Zaghib, Karim ;
Nazar, Linda F. .
ENERGY & ENVIRONMENTAL SCIENCE, 2013, 6 (06) :1772-1778
[2]  
Aetukuri NB, 2015, NAT CHEM, V7, P50, DOI [10.1038/NCHEM.2132, 10.1038/nchem.2132]
[3]   MECHANISM OF SUPEROXIDE ION DISPROPORTIONATION IN APROTIC-SOLVENTS [J].
ANDRIEUX, CP ;
HAPIOT, P ;
SAVEANT, JM .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1987, 109 (12) :3768-3775
[4]   The Effect of Oxygen Crossover on the Anode of a Li-O2 Battery using an Ether-Based Solvent: Insights from Experimental and Computational Studies [J].
Assary, Rajeev S. ;
Lu, Jun ;
Du, Peng ;
Luo, Xiangyi ;
Zhang, Xiaoyi ;
Ren, Yang ;
Curtiss, Larry A. ;
Amine, Khalil .
CHEMSUSCHEM, 2013, 6 (01) :51-55
[5]  
Aurbach D, 2016, NAT ENERGY, V1, DOI [10.1038/NENERGY.2016.128, 10.1038/nenergy.2016.128]
[6]   A critical review on lithium-air battery electrolytes [J].
Balaish, Moran ;
Kraytsberg, Alexander ;
Ein-Eli, Yair .
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2014, 16 (07) :2801-2822
[7]   TEMPO: A Mobile Catalyst for Rechargeable Li-O2 Batteries [J].
Bergner, Benjamin J. ;
Schuermann, Adrian ;
Peppler, Klaus ;
Garsuch, Arnd ;
Janek, Juergen .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2014, 136 (42) :15054-15064
[8]  
Black R., 2013, Angew. Chem. Int. Ed, V125, P410, DOI DOI 10.1002/ANGE201205354
[9]   Apparent molar volume, heat capacity, and conductance of lithium bis(trifluoromethylsulfone)imide in glymes and other aprotic solvents [J].
Brouillette, D ;
Perron, G ;
Desnoyers, JE .
JOURNAL OF SOLUTION CHEMISTRY, 1998, 27 (02) :151-182
[10]  
Bruce PG, 2012, NAT MATER, V11, P19, DOI [10.1038/nmat3191, 10.1038/NMAT3191]