Electrocatalytic four-electron reduction of oxygen to water by a highly flexible cofacial cobalt bisporphyrin

被引：168
作者：
Chang, CJ
Deng, YQ
Shi, CN
Chang, CK [1 ]
Anson, FC
Nocera, DG
机构：
[1] Michigan State Univ, Dept Chem, E Lansing, MI 48824 USA
[2] MIT, Dept Chem, Cambridge, MA 02139 USA
[3] CALTECH, Arthur Amos Noyes Lab Chem Phys, Div Chem & Chem Engn, Pasadena, CA 91125 USA
来源：
CHEMICAL COMMUNICATIONS | 2000年 / 15期
关键词：
D O I：
10.1039/b001620i
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Dicobalt(ii) cofacial bisporphyrins anchored by dibenzofuran (DPD) and xanthene (DPX) are efficient electrocatalysts for the four-electron reduction of oxygen to water despite their ca. 4 Angstrom difference in metal-metal distances, suggesting that the considerable longitudinal 'Pac-Man' flexibility of the pillared platforms is the origin for the similar catalytic reactivity of these structurally disparate systems.
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页码：1355 / 1356
页数：2
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