Synthesis and Diels-Alder reactions of 2-(buta-1,3-dien-2-yl)-5, 10,15,20-tetraphenylporphyrin

被引：16

作者：

Alonso, CMA ^{[1
]}

Neves, MGPMS ^{[1
]}

Tomé, AC ^{[1
]}

Silva, AMS ^{[1
]}

Cavaleiro, JAS ^{[1
]}

机构：

[1] Univ Aveiro, Dept Quim, P-3810193 Aveiro, Portugal

来源：

TETRAHEDRON LETTERS | 2000年 / 41卷 / 30期

关键词：

porphyrins; extrusion reactions; dienes; Diels-Alder reactions; Heck reactions;

D O I：

10.1016/S0040-4039(00)00923-0

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A new method for the introduction of a buta-1,3-dien-2-yl group in a beta-position of a porphyrin is described. The new beta-dienic porphyrin was used in Diels-Alder reactions with several dienophiles giving the corresponding adducts in good yields. (C) 2000 Elsevier Science Ltd. All rights reserved.

引用

页码：5679 / 5682

页数：4

共 9 条

[1] Reaction of beta-amino-meso-tetraphenylporphyrin with alpha beta-unsaturated carbonyl compounds: An approach to fused pyridinoporphyrins [J].