A new organic metal with thedithiooxalato-bridged anion network, β"-ET)2{[NMe3Ph]NaCr(C2S2O2)3(MeCN)}

被引：0

作者：

Zhilyaeva, EI ^{[1
]}

Shilov, GV

Bogdanova, OA

Lyubovskaya, RN

Lyubovskii, RB

Ovanesyan, NS

Aldoshin, SM

Train, C

Gruselle, M

机构：

[1] Russian Acad Sci, Inst Problems Chem Phys, Chernogolovka 142432, MD, Russia

[2] Univ Paris 06, Lab Chim Inorgan & Mat Mol, CNRS, Unite 7071, F-75252 Paris 05, France

来源：

MATERIALS SCIENCE-POLAND | 2004年 / 22卷 / 04期

关键词：

organic conductors; cation radical salt; electrical conductivity; X-ray diffraction;

D O I：

暂无

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

The synthesis, crystal structure, and conductivity of a new bis(ethylenedithio) tetrathiafulvalene (ET)-based cation radical salt with beta"-(ET)(2){[NMe3Ph] NaCr(C2S2O2)(3)(MeCN)} composition is described. The compound is metallic down to 60 K. In the structure, conducting donor layers with beta"- type packing alternate with {[NaCr(C2S2O2)(3)](2-)}(infinity) anionic networks and [NMe3Ph](+) organic cation layers.

引用

页码：565 / 569

页数：5

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