Synthesis of 1,4:3,6-Dianhydrohexitols Diesters from the Palladium-Catalyzed Hydroesterification Reaction

被引：13

作者：

Pruvost, Romain ^{[1
]}

Boulanger, Jerome ^{[2
]}

Leger, Bastien ^{[2
]}

Ponchel, Anne ^{[2
]}

Monflier, Eric ^{[2
]}

Ibert, Mathias ^{[3
]}

Mortreux, Andre ^{[1
]}

Chenal, Thomas ^{[1
]}

Sauthier, Mathieu ^{[1
]}

机构：

[1] Univ Lille 1, CNRS, UMR 8181, Unite Catalyse & Chim Solide,ENSCL, F-59650 Villeneuve Dascq, France

[2] Univ Artois, UMR 8181, Fac Sci Jean Perrin, F-62307 Lens, France

[3] Roquette Freres, F-62136 Lestrem, France

来源：

CHEMSUSCHEM | 2014年 / 7卷 / 11期

关键词：

diester; hydroesterification; isosorbide; olefin; palladium; CARBON-MONOXIDE; ISOSORBIDE; ESTERIFICATION; ALKENES; 1,4/3,6-DIANHYDRO-D-GLUCITOL; METHOXYCARBONYLATION; CARBONYLATION; COMPLEXES; ALKYNES; ETHENE;

D O I：

10.1002/cssc.201402584

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The hydroesterification of alpha olefins has been used to synthesize diesters from bio-based secondary diols: isosorbide, isomannide, and isoidide. The reaction was promoted by 0.2% palladium catalyst generated insitu from palladium acetate/triphenylphosphine/para-toluene sulfonic acid. Optimized reaction conditions allowed the selective synthesis of the diesters with high yields and the reaction conditions could be scaled up to the synthesis of hundred grams of diesters from isosorbide and 1-octene with solvent-free conditions.

引用

页码：3157 / 3163

页数：7

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