Short and stereoselective synthesis of the (-)-(5R, 6S)-6-acetoxyhexadecane-5-olide

被引：0

作者：

Sun, B

Peng, LZ

Chen, XS

Li, YL

Li, Y ^{[1
]}

机构：

[1] Lanzhou Univ, Inst Organ Chem, State Key Lab Appl Organ Chem, Lanzhou 730000, Peoples R China

[2] Lunan Pharmaceut Co Ltd, Linyi 276003, Peoples R China

来源：

CHINESE CHEMICAL LETTERS | 2004年 / 15卷 / 10期

关键词：

6-acetoxyhexadecan-5-olide; Baeyer-Villiger oxidation; aldol reaction; L-proline;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(-)-(5R, 6S)-6-Acetoxyhexadecan-5-olide 1, a natural mosquito attractant pheromone, was synthesized from readily available aldehyde 2 and cyclopentanone 3 using L-proline-catalyzed asymmetric aldol reaction as the key step.

引用

页码：1177 / 1178

页数：2

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