Efficient synthesis of triarylamines catalyzed by palladium/N-heterocyclic carbene

被引:17
作者
Chen, Chen
Li, Ying-Feng
Yang, Lian-Ming [1 ]
机构
[1] Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Lab New Mat, Beijing 100080, Peoples R China
[2] Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China
关键词
palladium catalysis; N-heterocyclic carbenes; N-arylation; triarylamines;
D O I
10.1016/j.molcata.2007.01.009
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A palladium(0)/imidazolium salt system as catalyst precursor proved to be effective, under the appropriately selected reaction conditions, for N-arylation of diarylamines and anilines with non-activated aryl bromides or chlorides to afford triarylamine derivatives. In most cases, excellent yields were achieved. (c) 2007 Elsevier B.V. All rights reserved.
引用
收藏
页码:158 / 162
页数:5
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