Brillouin light scattering of a fragile glass former: o-terphenyl

被引:10
作者
Monaco, G [1 ]
Comez, L
Fioretto, D
机构
[1] Univ Aquila, Dipartimento Fis, I-67100 Laquila, Italy
[2] Ist Nazl Fis Mat, I-16152 Genoa, Italy
[3] Univ Perugia, Dipartimento Fis, I-06100 Perugia, Italy
来源
PHILOSOPHICAL MAGAZINE B-PHYSICS OF CONDENSED MATTER STATISTICAL MECHANICS ELECTRONIC OPTICAL AND MAGNETIC PROPERTIES | 1998年 / 77卷 / 02期
关键词
D O I
10.1080/13642819808204974
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
We report Brillouin scattering measurements of the fragile glass former o-terphenyl over a wide temperature range covering the normal and the supercooled liquid phase down to the glass temperature. The velocity dispersion and the absorption of the longitudinal sound waves are reported and compared with literature data. The presence of both a residual sound speed dispersion in the hot liquid phase and a strongly asymmetric shape of the Brillouin linewidth curve in the high-temperature region indicates the existence of two relaxation phenomena: a structural and a fast secondary relaxation. This picture is consistent with the classification of o-terphenyl as a non-associated liquid, as emerges from the analysis of the temperature behaviour of the ratio of the experimental to the classically calculated sound wave absorption.
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页码:463 / 472
页数:10
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