A convenient synthesis of fluoroalkyl ketones and sulfones from perfluoroisopropyl iodide

被引：3

作者：

Chen, JG ^{[1
]}

Kirchmeier, RL ^{[1
]}

Shreeve, JM ^{[1
]}

机构：

[1] Univ Idaho, Dept Chem, Moscow, ID 83844 USA

来源：

JOURNAL OF FLUORINE CHEMISTRY | 1998年 / 89卷 / 01期

关键词：

diglyme; perfluoroisopropyl iodide; benzonitrile;

D O I：

10.1016/S0022-1139(98)00078-5

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

In the presence of hexaethylphosphorus triamide (HEPT), perfuoroisopropyl iodide is reacted directly with perfluoroalkyl acid halides, trifluoromethanesulfonyl fluoride, and methanesulfonyl chloride ir benzonitrile to give the corresponding fluorinated ketones and sulfones. Diglyme is the solvent of choice for the reaction of pentafluorobenzoyl chloride with perfluoroisopropyl iodide in the presence of HEPT. (C) 1998 Elsevier Science S.A.

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页码：5 / 8

页数：4

相关论文

共 19 条

[1] POLYFLUOROHETEROCYCLIC COMPOUNDS .14. SOME REACTIONS OF TETRAFLUOROISONICOTINIC ACID AND PENTAFLUOROBENZOIC ACID [J].

CHAMBERS, RD ;

HEATON, CA ;

MUSGRAVE, WK .

JOURNAL OF THE CHEMICAL SOCIETY C-ORGANIC, 1968, (15) :1933-&

[2]

CHAMBERS RD, 1968, J CHEM SOC C, P2394, DOI 10.1039/j39680002394

[3] SYNTHESIS AND REACTIONS OF A PERFLUOROALKYLETHER GRIGNARD-REAGENT CONTAINING A FUNCTIONAL ESTER GROUP [J].

CHEN, LS ;

CHEN, GJ ;

RYAN, MT ;

TAMBORSKI, C .

JOURNAL OF FLUORINE CHEMISTRY, 1987, 34 (3-4) :299-311

[4] FLUORO-KETONES .5. REACTIONS OF ALKYL AND ARYLLITHIUM COMPOUNDS WITH PERFLUOROALKYLETHER ESTERS [J].

CHEN, LS ;

TAMBORSKI, C .

JOURNAL OF FLUORINE CHEMISTRY, 1981, 19 (01) :43-53

[5]

ELNIGUMI YO, 1970, INORG NUCL CHEM, V32, P321

[6] PERFLUOROALKYL GRIGNARD AND GRIGNARD-TYPE REAGENTS .4. TRIFLUOROMETHYLMAGNESIUM IODIDE [J].

HASZELDINE, RN .

JOURNAL OF THE CHEMICAL SOCIETY, 1954, (APR) :1273-1279

[7] PERFLUOROALKYL DERIVATIVES OF SULFUR .15. PREPARATION AND CERTAIN REACTIONS OF METHYL POLYFLUOROALKYL SULFOXIDES AND SULFONES AND THEIR CONVERSION INTO POLYFLUOROALKANESULFONIC ACIDS [J].

HASZELDINE, RN ;

RIGBY, RB ;

TIPPING, AE .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1973, (07) :676-682

[8] A NOVEL NUCLEOPHILIC POLYFLUOROALKYLATING AGENT R(F)I-P(NET2)3 [J].

HUANG, WY ;

HU, CM ;

HE, YB ;

ZHOU, HF .

JOURNAL OF FLUORINE CHEMISTRY, 1990, 48 (01) :145-147

[9]

KOLOMEITSEV AA, 1990, SYNTHESIS-STUTTGART, P1151

[10] FLUORINATED TERTIARY ALCOHOLS AND ALKOXIDES FROM NUCLEOPHILIC TRIFLUOROMETHYLATION OF CARBONYL-COMPOUNDS [J].

KOTUN, SP ;

ANDERSON, JDO ;

DESMARTEAU, DD .

JOURNAL OF ORGANIC CHEMISTRY, 1992, 57 (04) :1124-1131