Sustainable electrochemical cross-dehydrogenative coupling of 4-quinolones and diorganyl diselenides

被引:91
作者
Chen, Jin-Yang [1 ]
Wu, Hong-Yu [3 ]
Gui, Qing-Wen [2 ]
Yan, Shan-Shu [2 ]
Deng, Jie [2 ]
Lin, Ying-Wu [1 ]
Cao, Zhong [3 ]
He, Wei-Min [1 ]
机构
[1] Univ South China, Sch Chem & Chem Engn, Hengyang 421001, Hunan, Peoples R China
[2] Yangtze Normal Univ, Coll Chem & Chem Engn, Chongqing 408000, Peoples R China
[3] Changsha Univ Sci & Technol, Hunan Prov Key Lab Mat Protect Elect Power & Tran, Changsha 410114, Hunan, Peoples R China
基金
中国国家自然科学基金;
关键词
Green chemistry; Cross-dehydrogenative coupling; Atom ecomnomy; Reusability; Electrochemistry; OXIDATIVE CYCLIZATION; H FUNCTIONALIZATION; METAL; ACCESS; QUINOXALIN-2(1H)-ONES; THIOCYANATION; HETEROCYCLES; DERIVATIVES; DISULFIDES; ALCOHOLS;
D O I
10.1016/S1872-2067(20)63750-0
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
An environmentally friendly method for the synthesis of 3-organylselenyl quinolones through the electrochemical cross-dehydrogenative coupling of 4-quinolones and diorganyl diselenides was developed. As a green, atom economic and self-separating process, the present reaction requires neither external oxidants nor electrolytes, forming a recyclable catalytic system. (C) 2021, Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved.
引用
收藏
页码:1445 / 1450
页数:6
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