Calcium-magnesium-alumina-silicate (CMAS) resistance property of BaLn2Ti3O10 (Ln=La, Nd) for thermal barrier coating applications

被引:30
作者
Guo, Lei [1 ,3 ]
Li, Mingzhu [1 ,2 ]
Yang, Chenxi [1 ,2 ]
Zhang, Chenglong [1 ,2 ]
Xu, Luming [1 ,2 ]
Ye, Fuxing [1 ,2 ,3 ]
Dan, Chengyi [4 ]
Ji, Vincent [4 ]
机构
[1] Tianjin Univ, Sch Mat Sci & Engn, Tianjin, Peoples R China
[2] Tianjin Univ, Tianjin Key Lab Adv Joining Technol, Tianjin, Peoples R China
[3] Tianjin Univ, Minist Educ, Key Lab Adv Ceram & Machining Technol, 92 Weijin Rd, Tianjin 300072, Peoples R China
[4] Univ Paris 11, ICMMO, SP2M, UMR CNRS 8182, F-91405 Orsay, France
基金
中国国家自然科学基金;
关键词
BaLn(2)Ti(3)O(10); Thermal barrier coatings (TBCs); Calcium-magnesium-alumina-silicate (CMAS); Crystallization; HIGH-TEMPERATURE ATTACK; GLASSY DEPOSITS; PHYSICAL PROPERTIES; MOLTEN CMAS; AIR; CERAMICS; MICROSTRUCTURE; CORROSION; SM; INFILTRATION;
D O I
10.1016/j.ceramint.2017.05.107
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Calcium-magnesium-alumina-silicate (CMAS) has posed enormous threat to thermal barrier coatings (TBCs). In this study, a series of newly developed TBC ceramics, BaLn(2)Ti(3)O(10) (Ln=La, Nd), are found to have high resistance to the penetration of molten CMAS at 1250 degrees C. The formation of a continuous, dense crystalline layer, mainly composed of apatite and CaTiO3 phases, on the sample surfaces contributed to this desirable attribute. The accumulation of Ba in the molten CMAS triggered the crystallization of the melt, leading to the formation of many BaAl2Si2O8 celsian crystals above the crystalline layer, which could reduce the mobility of the molten CMAS. The mechanisms by which the CMAS attacks BaLn(2)Ti(3)O(10) samples are discussed. The results indicate that Ba is an effective element for altering CMAS composition, and doping Ba in TBCs might be an attractive way of mitigating CMAS attack.
引用
收藏
页码:10521 / 10527
页数:7
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