Advancing towards a veritable calcium-ion battery: CaCo2O4 positive electrode material

被引：124

作者：

Cabello, Marta ^{[1
]}

Nacimiento, Francisco ^{[1
]}

Gonzalez, Jose R. ^{[1
]}

Ortiz, Gregorio ^{[1
]}

Alcantara, Ricardo ^{[1
]}

Lavela, Pedro ^{[1
]}

Perez-Vicente, Carlos ^{[1
]}

Tirado, Jose L. ^{[1
]}

机构：

[1] Univ Cordoba, Lab Quim Inorgan, Edificio C3,Campus Rabanales, E-14071 Cordoba, Spain

来源：

ELECTROCHEMISTRY COMMUNICATIONS | 2016年 / 67卷

关键词：

Post-lithium batteries; Calcium; CaCo2O4; V2O5; Intercalation; INTERCALATION; SYSTEM;

D O I：

10.1016/j.elecom.2016.03.016

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

A veritable calcium-ion battery using CaCo2O4 (s.g. P2/m) as a positive electrode, V2O5 (s.g. Pmmn) as a negative electrode and calcium perchlorate in acetonitrile as electrolyte solution has been evaluated for the first time. The electrochemical tests, XRD results and X-ray photoelectron spectra confirm that the calcium ion can be firstly removed from CaCo2O4 and then reintercalated, and this material can be an interesting candidate for developing non-aqueous calcium-ion batteries. (C) 2016 Elsevier B.V. All rights reserved.

引用

页码：59 / 64

页数：6

共 23 条

[1] CoO2, the end member of the LixCoO2 solid solution [J].

Amatucci, GG ;

Tarascon, JM ;

Klein, LC .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1996, 143 (03) :1114-1123

[2] Investigation of yttrium and polyvalent ion intercalation into nanocrystalline vanadium oxide [J].

Amatucci, GG ;

Badway, F ;

Singhal, A ;

Beaudoin, B ;

Skandan, G ;

Bowmer, T ;

Plitza, I ;

Pereira, N ;

Chapman, T ;

Jaworski, R .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2001, 148 (08) :A940-A950

[3] Vanadium oxide-propylene carbonate composite as a host for the intercalation of polyvalent cations [J].

Bervas, M ;

Klein, LC ;

Amatucci, GG .

SOLID STATE IONICS, 2005, 176 (37-38) :2735-2747

[4]

Blangero M., 2008, THESIS U SCI TECHNOL

[5] Topotactic routes to layered calcium cobalt oxides [J].

Cushing, BL ;

Wiley, JB .

JOURNAL OF SOLID STATE CHEMISTRY, 1998, 141 (02) :385-391

[6] Defective Graphene as a High-Capacity Anode Material for Na- and Ca-Ion Batteries [J].

Datta, Dibakar ;

Li, Junwen ;

Shenoy, Vivek B. .

ACS APPLIED MATERIALS & INTERFACES, 2014, 6 (03) :1788-1795

[7] XPS analysis of new lithium cobalt oxide thin-films before and after lithium deintercalation [J].

Dupin, JC ;

Gonbeau, D ;

Benqlilou-Moudden, H ;

Vinatier, P ;

Levasseur, A .

THIN SOLID FILMS, 2001, 384 (01) :23-32

[8] Electrochemical insertion/extraction of calcium ions using crystalline vanadium oxide [J].

Hayashi, M ;

Arai, H ;

Ohtsuka, H ;

Sakurai, Y .

ELECTROCHEMICAL AND SOLID STATE LETTERS, 2004, 7 (05) :A119-A121

[9] Electrochemical characteristics of calcium in organic electrolyte solutions and vanadium oxides as calcium hosts [J].

Hayashi, M ;

Arai, H ;

Ohtsuka, H ;

Sakurai, Y .

JOURNAL OF POWER SOURCES, 2003, 119 :617-620

[10] Phase transitions in the LiNi0.5Mn0.5O2 system with temperature [J].

Hinuma, Yoyo ;

Meng, Ying S. ;

Kang, Kisuk ;

Ceder, Gerbrand .

CHEMISTRY OF MATERIALS, 2007, 19 (07) :1790-1800

← 1 2 3 →