Comments on "Solubility and solution thermodynamics of 2,3,4,5-tetrabromothiophene in (ethanol plus trichloromethane) binary solvent mixtures"

被引:3
作者
Jouyban, Abolghasem [1 ,2 ,3 ]
Martinez, Fleming [4 ]
Acree, William E., Jr. [5 ]
机构
[1] Tabriz Univ Med Sci, Pharmaceut Anal Res Ctr, Tabriz 51664, Iran
[2] Tabriz Univ Med Sci, Fac Pharm, Tabriz 51664, Iran
[3] Tabriz Univ Med Sci, Kimia Idea Pardaz Azarbayjan KIPA Sci Based Co, Tabriz 51664, Iran
[4] Univ Nacl Colombia, Fac Ciencias, Dept Farm, Grp Invest Farrnaceut Fisicoquim, Cra 30 No 45-03, Bogota, Colombia
[5] Univ N Texas, Dept Chem, Denton, TX 76203 USA
关键词
Solubility; Binary solvent mixtures; Preferential solvation; Inverse Kirkwood-Buff integrals; SOLVATOCHROMIC COMPARISON METHOD; PREFERENTIAL SOLVATION; SCALE;
D O I
10.1016/j.fluid.2016.03.023
中图分类号
O414.1 [热力学];
学科分类号
摘要
Several mathematical errors and shortcomings in the paper by Yang and coworkers [Fluid Phase Equilib. 363 (2014) 276-281] are discussed. The solubility data for 2,3,4,5-tetrabromothiophene dissolved in binary ethanol + trichloromethane solvent mixtures is used to describe the preferential solvation around the dissolved solute. (C) 2016 Elsevier B.V. All rights reserved.
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页码:88 / 92
页数:5
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