Low temperature heat capacity of Nd2Zr2O7 pyrochlore

被引：58
作者：
Lutique, S
Javorsky, P
Konings, RJM
van Genderen, ACG
van Miltenburg, JC
Wastin, F
机构：
[1] Commiss European Communities, Joint Res Ctr, Inst Transuranium Elements, D-76125 Karlsruhe, Germany
[2] Univ Utrecht, Chem Thermodynam Grp, NL-3584 CH Utrecht, Netherlands
来源：
JOURNAL OF CHEMICAL THERMODYNAMICS | 2003年 / 35卷 / 06期
关键词：
pyrochlore; neodymium zirconate; heat capacity; thermodynamic properties;
D O I：
10.1016/S0021-9614(03)00040-5
中图分类号：
O414.1 [热力学];
学科分类号：
摘要：
Heat capacity of neodymium zirconate (Nd2Zr2O7). with pyrochlore structure was measured by adiabatic calorimetry and the hybrid adiabatic relaxation method in the temperature range (0.45 to 400) K. Its excess component was obtained by comparison with the heat capacity of the lanthanum zirconate. A thermal anomaly was observed below T = 7.2 K. From the heat capacity measurements, the thermodynamic functions of Nd2Zr2O7 were determined. (C) 2003 Elsevier Science Ltd. All rights reserved.
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页码：955 / 965
页数：11
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