Electrochemical Synthesis, Properties, and Structure of 1,10-Phenanthroline Adducts of Mononuclear Copper, Cobalt, and Nickel Chelates in the N,N,O-Ligand Environment

被引：4

作者：

Garnovskii, D. A. ^{[1
]}

Vlasenko, V. G. ^{[2
]}

Aleksandrov, G. G. ^{[3
]}

Levchenkov, S. I. ^{[1
]}

Makarova, N. I. ^{[4
]}

Koshchienko, Yu. V. ^{[4
]}

Uraev, A. I. ^{[4
]}

Burlov, A. S. ^{[4
]}

机构：

[1] Russian Acad Sci, Southern Sci Ctr, Rostov Na Donu 344006, Russia

[2] Russian Acad Sci, Res Inst Phys, Rostov Na Donu 344090, Russia

[3] Russian Acad Sci, Kurnakov Inst Gen & Inorgan Chem, Moscow 119991, Russia

[4] Southern Fed Univ, Res Inst Phys & Organ Chem, Rostov Na Donu 344090, Russia

来源：

RUSSIAN JOURNAL OF COORDINATION CHEMISTRY | 2018年 / 44卷 / 10期

基金：

俄罗斯基础研究基金会;

关键词：

electrosynthesis; mixed-ligand complexes; 1,10-phenanthroline; tridentate Schiff bases; X-ray diffraction; COMPLEXES; CRYSTAL; PYRAZOLE; CU(II); ZINC;

D O I：

10.1134/S1070328418100032

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

1,10-Phenanthroline (Phen) adducts [M(L)Phen] in copper(II), cobalt(II), and zinc(II) chelates based on N,N,O-tridentate tosylamino-functionalized pyrazole-containing Schiff base (H2L), resulting from condensation of 2-tosylaminoaniline with 3-methyl-1-phenyl-4-formylpyrazol-5-ol, were obtained by electrosynthesis. The composition and structure of the mixed-ligand complexes were confirmed by elemental analysis, IR spectroscopy, and magnetochemical measurements. The structures of azomethine H2L and mixed-ligand copper(II) complex were determined by X-ray diffraction.

引用

页码：596 / 603

页数：8

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