Reductive arene ortho-silanolization of aromatic esters with hydridosilyl acetals

被引：16

作者：

Hua, Yuanda ^{[1
]}

Asgari, Parham ^{[1
]}

Dakarapu, Udaya Sree ^{[1
]}

Jeon, Junha ^{[1
]}

机构：

[1] Univ Texas Arlington, Dept Chem & Biochem, Arlington, TX 76019 USA

来源：

CHEMICAL COMMUNICATIONS | 2015年 / 51卷 / 18期

关键词：

C-H SILYLATION; CATALYZED REGIOSELECTIVE SILYLATION; CROSS-COUPLING REACTIONS; DIRECTING GROUP; BOND; SILICON; HYDROGEN; ARYL; ACTIVATION; OXIDATION;

D O I：

10.1039/c4cc09850a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

This work describes the design and application of a single-pot, reductive arene C-H silanolization of aromatic esters for synthesis of ortho-formyl arylsilanols. This strategy involves a sequence of two transition metal (Ir and Rh)-catalyzed reactions for reductive arene ortho-silylation directed by hydridosilyl acetals and hydrolysis.

引用

页码：3778 / 3781

页数：4

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