Strengthening mechanism of CoCrNiMox high entropy alloys by high-throughput nanoindentation mapping technique

被引:32
作者
Tong, Yonggang [1 ]
Zhang, Hao [1 ]
Huang, Hongfeng [2 ]
Yang, Lingwei [3 ]
Hu, Yongle [1 ]
Liang, Xiubing [4 ]
Hua, Manyu [1 ]
Zhang, Jian [1 ]
机构
[1] Changsha Univ Sci & Technol, Coll Automobile & Mech Engn, Changsha 410114, Peoples R China
[2] Guilin Univ Technol, Coll Mat Sci & Engn, Guilin 541004, Peoples R China
[3] China Aerodynam Res & Dev Ctr, Hyperveloc Aerodynam Inst, Mianyang 621000, Sichuan, Peoples R China
[4] Acad Mil Sci PLA China, Natl Inst Def Technol Innovat, Beijing 100071, Peoples R China
基金
国家重点研发计划; 中国国家自然科学基金;
关键词
A; high-entropy alloys; B; mechanical properties; D; microstructurex; microstructure F; nanoindentation; DESIGN;
D O I
10.1016/j.intermet.2021.107209
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A novel nanoindentation mapping technique was employed to correlate the microstructure, composition and mechanical properties of the fcc, laves and lamellae in CoCrNiMox high-entropy alloys with varying Mo content. The results suggest that the Young's modulus of the 3 constituents were comparable, averaging X230 GPa. Despite this, the hardness was quite different. The fcc phase in CoCrNiMox was mainly strengthened by a solute strengthening mechanism, and the hardness was increased from X3.98 GPa to X4.45 GPa, as the atomic percentage of Mo in fcc increased from X7.4% to 15.4%. A solute strengthening model a accounting lattice distortion was employed to correlate the strengthening effect in fcc with Mo content. The laves phase was rich in Mo composition (X28.6%) and exhibited an ultrahigh hardness, X9.13 GPa, which was X2 times higher than that of fcc phase. Finally, the lamellae colonies, made up by alternative fcc and laves phases, had an intermediate hardness, X6.36 GPa. This was well explained by a rule-of-mixture model.
引用
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页数:7
相关论文
共 24 条
[1]   A review on nano-/ultrafine advanced eutectic alloys [J].
Chanda, Barnasree ;
Potnis, Gaurav ;
Jana, Parijat P. ;
Das, Jayanta .
JOURNAL OF ALLOYS AND COMPOUNDS, 2020, 827
[2]   Fracture of sigma phase containing Co-Cr-Ni-Mo medium entropy alloys [J].
Chung, D. H. ;
Liu, X. D. ;
Yang, Y. .
JOURNAL OF ALLOYS AND COMPOUNDS, 2020, 846
[3]   Precision lattice constants from x-ray powder photographs [J].
Cohen, MU .
REVIEW OF SCIENTIFIC INSTRUMENTS, 1935, 6 (03) :68-74
[4]   Effects of Tungsten Addition on the Microstructure and Mechanical Properties of Near-Eutectic AlCoCrFeNi2 High-Entropy Alloy [J].
Dong, Yong ;
Lu, Yiping .
JOURNAL OF MATERIALS ENGINEERING AND PERFORMANCE, 2018, 27 (01) :109-115
[5]   Critical comments to the Oliver-Pharr measurement technique of hardness and elastic modulus by instrumented indentations and refinement of its basic relations [J].
Galanov, B. A. ;
Dub, S. N. .
JOURNAL OF SUPERHARD MATERIALS, 2017, 39 (06) :373-389
[6]   A fracture-resistant high-entropy alloy for cryogenic applications [J].
Gludovatz, Bernd ;
Hohenwarter, Anton ;
Catoor, Dhiraj ;
Chang, Edwin H. ;
George, Easo P. ;
Ritchie, Robert O. .
SCIENCE, 2014, 345 (6201) :1153-1158
[7]   A precipitation-hardened high-entropy alloy with outstanding tensile properties [J].
He, J. Y. ;
Wang, H. ;
Huang, H. L. ;
Xu, X. D. ;
Chen, M. W. ;
Wu, Y. ;
Liu, X. J. ;
Nieh, T. G. ;
An, K. ;
Lu, Z. P. .
ACTA MATERIALIA, 2016, 102 :187-196
[8]   Effects of Ta addition on the microstructures and mechanical properties of CoCrFeNi high entropy alloy [J].
Jiang, Hui ;
Han, Kaiming ;
Qiao, Dongxu ;
Lu, Yiping ;
Cao, Zhiqiang ;
Li, Tingju .
MATERIALS CHEMISTRY AND PHYSICS, 2018, 210 :43-48
[9]   A new strategy to design eutectic high-entropy alloys using simple mixture method [J].
Jiang, Hui ;
Han, Kaiming ;
Gao, Xiaoxia ;
Lu, Yiping ;
Cao, Zhiqiang ;
Gao, Michael C. ;
Hawk, Jeffrey A. ;
Li, Tingju .
MATERIALS & DESIGN, 2018, 142 :101-105
[10]   Mechanically alloyed Mo-Si-B alloys with a continuous α-Mo matrix and improved mechanical properties [J].
Krueger, M. ;
Franz, S. ;
Saage, H. ;
Heilmaier, M. ;
Schneibel, J. H. ;
Jehanno, P. ;
Boening, M. ;
Kestler, H. .
INTERMETALLICS, 2008, 16 (07) :933-941