Synthesis, Structure and Properties of Donor-acceptor-type [4]Dendralenes

被引：0
作者：
Matsumoto, Yuya [1 ]
Matsuda, Rina [1 ]
Yoshimura, Aya [1 ,2 ]
Shirahata, Akashi [1 ,2 ,3 ]
Misaki, Yohji [1 ,2 ,3 ]
机构：
[1] Ehime Univ, Grad Sch Sci & Engn, Dept Appl Chem, 3 Bunkyo cho, Matsuyama, Ehime 7908577, Japan
[2] Ehime Univ, Res Unit Power Generat & Storage Mat, Matsuyama, Ehime 7908577, Japan
[3] Ehime Univ, Res Unit Dev Organ Superconductors, Matsuyama, Ehime 7908577, Japan
来源：
CHEMISTRY LETTERS | 2022年 / 51卷 / 05期
关键词：
Dendralene; X-ray structure analysis; Cyclic voltammetry; X-RAY; TETRACYANOETHYLENE TCNE; TETRATHIAFULVALENE TTF; OPTICAL-PROPERTIES; CHARGE-TRANSFER; 1,3-DITHIOL-2-YLIDENE; ELECTROCHEMISTRY; REFINEMENT; ANALOGS; SYSTEMS;
D O I：
10.1246/cl.220064
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
[4]Dendralene and its analogs possessing both strongly electron-donating 1,3-dithiol-2-ylidenes and electron-accepting dicyanomethylidenes (2b-4b) were successfully synthesized. X-ray structure analysis revealed that 2b adopts a nonplanar structure, in which half units of 2b are significantly inclined to each other. Cyclic voltammograms of 2b-4b consisted of one pair of two-electron oxidation waves and one pair of one-electron reduction waves.
引用
收藏
页码：581 / 584
页数：4
相关论文
共 33 条
  • [1] Synthesis, structure, and optical properties of 1,4-dithiafulvene-based nonlinear optic-phores
    Alias, Silvia
    Andreu, Raquel
    Blesa, Maria Jesus
    Franco, Santiago
    Garin, Javier
    Gragera, Aurora
    Orduna, Jesus
    Romero, Pilar
    Villacampa, Belen
    Allain, Magali
    [J]. JOURNAL OF ORGANIC CHEMISTRY, 2007, 72 (17) : 6440 - 6446
  • [2] Dendralene-type TTF vinylogs containing a 1,3-diselenole ring
    Amaresh, RR
    Liu, DZ
    Konovalova, T
    Lakshmikantham, MV
    Cava, MP
    Kispert, LD
    [J]. JOURNAL OF ORGANIC CHEMISTRY, 2001, 66 (23) : 7757 - 7764
  • [3] Bryce MR, 2000, CHEM-EUR J, V6, P1955, DOI 10.1002/1521-3765(20000602)6:11<1955::AID-CHEM1955>3.3.CO
  • [4] 2-2
  • [5] DEGREE OF CHARGE-TRANSFER IN ORGANIC CONDUCTORS BY INFRARED-ABSORPTION SPECTROSCOPY
    CHAPPELL, JS
    BLOCH, AN
    BRYDEN, WA
    MAXFIELD, M
    POEHLER, TO
    COWAN, DO
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1981, 103 (09) : 2442 - 2443
  • [6] A NEW REFINEMENT OF MONOCLINIC TETRACYANOETHYLENE (TCNE) FROM X-RAY AND NEUTRON DATA
    DRUCK, U
    GUTH, H
    [J]. ZEITSCHRIFT FUR KRISTALLOGRAPHIE, 1982, 161 (1-2): : 103 - 110
  • [7] Vilsmeier-Haack Type Formylation on 6-Aryl-1,4-dithiafulvenes and Syntheses of Novel Extended Tetrathiafulvalene Donors
    Fujioka, Atsushi
    Kubo, Takashi
    Watanabe, Miho
    Ueda, Masafumi
    Miyamoto, Hisakazu
    Misaki, Yohji
    [J]. SYNTHESIS-STUTTGART, 2016, 48 (06): : 845 - 854
  • [8] First fused perpendicular hybrid tetrathiafulvalene (TTF) dimers:: A new strategy in π-extended and rigidified TTF
    Gautier, N
    Gallego-Planas, N
    Mercier, N
    Levillain, E
    Hudhomme, P
    [J]. ORGANIC LETTERS, 2002, 4 (06) : 961 - 963
  • [9] Oligomeric and polymeric systems with a cross-conjugated π-framework
    Gholami, Mojtaba
    Tykwinski, Rik R.
    [J]. CHEMICAL REVIEWS, 2006, 106 (12) : 4997 - 5027
  • [10] Dye-Sensitized Solar Cells
    Hagfeldt, Anders
    Boschloo, Gerrit
    Sun, Licheng
    Kloo, Lars
    Pettersson, Henrik
    [J]. CHEMICAL REVIEWS, 2010, 110 (11) : 6595 - 6663
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