Research on Photochromic Materials with Synthesis and Properties of 1-(2-Methyl-3-benzothiophene)-2-[2-methyl-5-(3-cyanophenyl)-3-thienyl]perfluorocyclopentene

被引：0
|
作者：
Liao, Guanming [1 ]
Zheng, Chunhong [1 ]
Pu, Shouzhi [1 ]
机构：
[1] Jiangxi Sci & Technol Normal Univ, Jiangxi Key Lab Organ Chem, Nanchang 330013, Peoples R China
来源：
MECHANICAL ENGINEERING, MATERIALS AND INFORMATION TECHNOLOGY II | 2014年 / 662卷
关键词：
Diarylethene; Photochromic; Fluorescence; Benzothiophene moiety; MOLECULAR SWITCHES; DIARYLETHENE; PHOTOCHEMISTRY;
D O I：
10.4028/www.scientific.net/AMM.662.95
中图分类号：
TH [机械、仪表工业];
学科分类号：
0802 ;
摘要：
An asymmetrical photochromic diarylethene1-(2-Methyl-3-benzothiophene)-2-[2-methyl-5-(3-cyanophenyl)-3-thienyl]perfluorocyclopentene (1o) was synthesized and its phtochromic, fluorescent properties in both solution and PMMA films were investigated in detail. This compound exhibited remarkable photochromism, upon irradiation with 297 nm UV light, the colorless solution of 1o turned to violet with a new visible absorption band centered at 535 nm (epsilon = 1.08 x 10(4) L mol(-1) cm(-1)) attributable to the closed-ring isomer 1c. The emission intensity of diarylethene 1o in a photostationary state was quenched to ca. 32% in hexane and 43% in PMMA film.
引用
收藏
页码：95 / 98
页数：4
相关论文
共 50 条
  • [31] Synthesis and Properties of 1-(2-methyl-5-(4-tolyl)-3-thienyl)-2-[2-methyl-5-(4-n-pentylphenyl)-3-thienyl] Perfluoroyclopentene
    Liu, Peng
    Dong, Xiaorong
    Duan, Fang
    Pu, Shouzhi
    PROCEEDINGS OF THE 2015 INTERNATIONAL CONFERENCE ON MATERIALS CHEMISTRY AND ENVIRONMENTAL PROTECTION (MEEP-15), 2016, 4
  • [32] Synthesis and Properties Study of 1-(2,4-dimethoxyl-5-pyrimidinyl)-2-[2-methyl-5-(3-cyanphenyl)-3-thienyl]perfluorocyclopentene
    Cui, S. Q.
    Liu, J. J.
    Liu, H. L.
    2015 2ND INTERNATIONAL CONFERENCE ON MATERIAL ENGINEERING AND APPLICATION (ICMEA 2015), 2015, : 238 - 242
  • [33] Synthesis and Properties of a New Unsymmetry Diarylethene 1-[2-methyl-5-(3-fluorophenyl)-3-thienyl]-2-[2-methyl-5-(3-fluoro-4-chloro)phenyl-3-thienyl] Perfluorocyclopentene
    Qu, S. Z.
    Zheng, C. H.
    Pu, S. Z.
    3RD INTERNATIONAL CONFERENCE ON ADVANCED COMPOSITE MATERIALS AND MANUFACTURING ENGINEERING (CMME 2015), 2015, : 68 - 71
  • [34] Synthesis and Photochromic Properties of 1-(2-methyl-1-phenyl)-2-[2-methyl-5-(4-formylphenyl)-3-thienyl]perfluoroyclopentene
    Zhang, Xiaodong
    Wei, Shasha
    Pu, Shouzhi
    ADVANCED RESEARCH ON MATERIAL SCIENCE, ENVIROMENT SCIENCE AND COMPUTER SCIENCE III, 2014, 886 : 183 - 186
  • [35] Synthesis and Properties of 1-[2-methyl-5-(9-anthracyl)-3-thienyl]-2-[2-methyl-5-(4-n-pentyl phenyl)-3-thienyl]perfluoroyclopentene
    Liu, Peng
    Liu, Hong-Liang
    Zhang, Zhi-Hui
    PROCEEDINGS OF THE 4TH 2016 INTERNATIONAL CONFERENCE ON MATERIAL SCIENCE AND ENGINEERING (ICMSE 2016), 2016, 101 : 105 - 108
  • [36] SYNTHESIS AND APPLICATION OF 1-[2-METHYLBENZENE]-2-[2-METHYL-5-(4-PROPYLPHENYL)-3-THIENYL] PERFLUOROCYCLOPENTENE
    Feng, Er-Ting
    Xue, Ya-Ming
    Pu, Shou-Zhi
    MATERIAL ENGINEERING AND MECHANICAL ENGINEERING (MEME2015), 2016, : 1469 - 1475
  • [37] Synthesis and Photochromic Properties of Diarylethene 1-[2-methyl-5-phenyl-3-thienyl]-2-[2-methyl-5-(3-fluoro-4-chloro)phenyl-3-thienyl]perfluorocyclopentene
    Xue, D. D.
    Chen, B.
    Zheng, C. H.
    Pu, S. Z.
    2015 2ND INTERNATIONAL CONFERENCE ON MATERIAL ENGINEERING AND APPLICATION (ICMEA 2015), 2015, : 284 - 288
  • [38] Synthesis and Properties Study of 1-(2,4-dimethoxyl-5-pyrimidinyl)-2-[2-methyl-5-(3-methylbenzene)-3-thienyl]perfluorocyclopentene
    Liu, Jingjing
    Jia, Hongjing
    Pu, Shouzhi
    ADVANCED RESEARCH ON MATERIAL SCIENCE, ENVIROMENT SCIENCE AND COMPUTER SCIENCE III, 2014, 886 : 164 - 167
  • [39] Synthesis and Photochromism Studies of 1-[2-methyl-5-(2-methoxylphenyl)-3-thienyl]-2-[2-methyl-(5-ethynyl)trimethylsilane-3-thienyl]perfluorocyclopentene
    Lu, R. M.
    Tian, Z. Y.
    Cui, S. Q.
    Pu, S. Z.
    3RD INTERNATIONAL CONFERENCE ON ADVANCED COMPOSITE MATERIALS AND MANUFACTURING ENGINEERING (CMME 2015), 2015, : 64 - 67
  • [40] Synthesis and Characterization of Photochromic 1-(3,5-dimethyl-4-isoxazolyl)-2[2-methyl-5-(3-methylphenyl)-3-thienyl] perfluorocyclopentene
    Li, Hui
    Pu, Shouzhi
    Cui, Shiqiang
    ADVANCES IN MATERIALS SCIENCE-BOOK, 2011, 327 : 45 - 48
12345