Cu3V10O28•24H2O and CuNa4V10O28•23H2O

被引：13

作者：

Iida, A ^{[1
]}

Ozeki, T ^{[1
]}

机构：

[1] Tokyo Inst Technol, Dept Chem & Mat Sci, Meguro Ku, Tokyo 1528551, Japan

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 2003年 / 59卷

关键词：

D O I：

10.1107/S0108270103008552

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The crystal structures of tricopper decavanadate tetracosahydrate, (I), and copper tetrasodium decavanadate tricosahydrate, (II), have been determined by single-crystal X- ray diffraction. Both compounds exhibit a catenary structure consisting of [V10O28](6-). anions linked by Cu2+ cations in (I) or by Na+ cations in (II). Compound (II) also contains a polymeric linear array of edge-sharing [Na(OH2)(6)](+) and [Cu(OH2)(6)](2+) octahedra. In both compounds, the [V10O28](6-) ions lie about inversion centres and the Cu2+ ions in (I) also lie about inversion centers.

引用

页码：I41 / I44

页数：4

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