Dearomative Cascade Photocatalysis: Divergent Synthesis through Catalyst Selective Energy Transfer

被引：160

作者：

James, Michael J. ^{[1
]}

Schwarz, Jonas Luca ^{[1
]}

Strieth-Kalthoff, Felix ^{[1
]}

Wibbeling, Birgit ^{[1
]}

Glorius, Frank ^{[1
]}

机构：

[1] Westfalische Wilhelms Univ Munster, Organ Chem Inst, Corrensstr 40, D-48149 Munster, Germany

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2018年 / 140卷 / 28期

关键词：

INTERMOLECULAR 2+2 PHOTOCYCLOADDITION; VISIBLE-LIGHT PHOTOCATALYSIS; DIELS-ALDER CYCLOADDITIONS; Z ISOMERIZATION; CYCLIZATION; REARRANGEMENT; EXPLORATION; ANNULATION; MECHANISM; PRODUCTS;

D O I：

10.1021/jacs.8b03302

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The discovery and application of dearomative cascade photocatalysis as a strategy in complex molecule synthesis is described. Visible-light-absorbing photosensitizers were used to (sequentially) activate a 1 naphthol derived arene precursor to divergently form two different polycyclic molecular scaffolds through catalyst selective energy transfer.

引用

页码：8624 / 8628

页数：5

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