Dearomative Cascade Photocatalysis: Divergent Synthesis through Catalyst Selective Energy Transfer

被引：149
作者：
James, Michael J. [1 ]
Schwarz, Jonas Luca [1 ]
Strieth-Kalthoff, Felix [1 ]
Wibbeling, Birgit [1 ]
Glorius, Frank [1 ]
机构：
[1] Westfalische Wilhelms Univ Munster, Organ Chem Inst, Corrensstr 40, D-48149 Munster, Germany
来源：
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2018年 / 140卷 / 28期
关键词：
INTERMOLECULAR 2+2 PHOTOCYCLOADDITION; VISIBLE-LIGHT PHOTOCATALYSIS; DIELS-ALDER CYCLOADDITIONS; Z ISOMERIZATION; CYCLIZATION; REARRANGEMENT; EXPLORATION; ANNULATION; MECHANISM; PRODUCTS;
D O I：
10.1021/jacs.8b03302
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The discovery and application of dearomative cascade photocatalysis as a strategy in complex molecule synthesis is described. Visible-light-absorbing photosensitizers were used to (sequentially) activate a 1 naphthol derived arene precursor to divergently form two different polycyclic molecular scaffolds through catalyst selective energy transfer.
引用
收藏
页码：8624 / 8628
页数：5
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