Electrocatalysis at graphite and carbon nanotube modified electrodes: edge-plane sites and tube ends are the reactive sites

被引：965

作者：

Banks, CE ^{[1
]}

Davies, TJ ^{[1
]}

Wildgoose, GG ^{[1
]}

Compton, RG ^{[1
]}

机构：

[1] Univ Oxford, Phys & Theoret Chem Lab, Oxford OX1 3QZ, England

来源：

CHEMICAL COMMUNICATIONS | 2005年 / 07期

关键词：

D O I：

10.1039/b413177k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Carbon, and particularly graphite in its various forms, is an attractive electrode material. Two areas of particular interest are modified carbon electrodes and carbon nanotube electrodes. In this article we focus on the relationship between surface structure and electrochemical and chemical reactivity of electrodes based on these materials. We overview recent work in this area which has led us to believe that much of the catalytic activity, electron transfer and chemical reactivity of graphitic carbon electrodes is at surface defect sites, and in particular edge-plane-like defect sites. We also question the claimed special "catalytic'' properties of carbon nanotube modified electrodes.

引用

页码：829 / 841

页数：13

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