Microstructures and microwave dielectric characteristics of Ca(Zn1/3Nb2/3)O3 complex perovskite ceramics

被引:48
作者
Chen, XM [1 ]
Liu, D [1 ]
Hou, RZ [1 ]
Hu, X [1 ]
Liu, XQ [1 ]
机构
[1] Zhejiang Univ, Dept Mat Sci & Engn, Hangzhou 310027, Peoples R China
关键词
D O I
10.1111/j.1151-2916.2004.tb07492.x
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Ca(Zn1/3Nb2/3)O-3 microwave dielectric ceramics were prepared using a solid-state reaction process, and their microwave dielectric properties were evaluated as functions of sintering and postdensification annealing conditions. The relationship between microwave dielectric properties and processing was interpreted through the variation of microstructures. The dielectric constant showed slight variation with sintering and annealing conditions, but the QxF value increased at first and then decreased with increased sintering temperature, and annealing in oxygen indicated significant improvement in QxF, especially for the specimens sintered at higher temperatures. The good microwave dielectric properties were obtained in the ceramics sintered at 1225degreesC in air for 3 h and annealed at 1100degreesC in oxygen for 8 h: epsilon = 34.1, QxF = 15 890 GHz, tau(f) = -48 ppm/degreesC.
引用
收藏
页码:2208 / 2212
页数:5
相关论文
共 12 条
[1]  
CHEN XB, 1994, P SOC NUTR PHYSL, V3, P244
[2]  
Davies PK, 1997, J AM CERAM SOC, V80, P1727, DOI 10.1111/j.1151-2916.1997.tb03046.x
[3]   SIMPLE WAYS OF DETERMINING PEROVSKITE STRUCTURES [J].
GLAZER, AM .
ACTA CRYSTALLOGRAPHICA SECTION A, 1975, 31 (NOV1) :756-762
[4]  
Hakki B. W., 1960, IEEE Trans. Microwave Theory Techn, V8, P402, DOI DOI 10.1109/TMTT.1960.1124749
[5]   Improved high Q value of CaTiO3-Ca(Mg1/3Nb2/3)O3 solid solution with near zero temperature coefficient of resonant frequency [J].
Huang, CL ;
Chen, HL ;
Wu, CC .
MATERIALS RESEARCH BULLETIN, 2001, 36 (09) :1645-1652
[6]   Dielectric properties of CaTiO3-Ca(Mg1/3Nb2/3)O3 ceramic system at microwave frequency [J].
Huang, CL ;
Yang, RY ;
Weng, MH .
JAPANESE JOURNAL OF APPLIED PHYSICS PART 1-REGULAR PAPERS SHORT NOTES & REVIEW PAPERS, 2000, 39 (12A) :6608-6611
[7]   DIELECTRIC-PROPERTIES OF CA-BASED COMPLEX PEROVSKITE AT MICROWAVE-FREQUENCIES [J].
KAGATA, H ;
KATO, J .
JAPANESE JOURNAL OF APPLIED PHYSICS PART 1-REGULAR PAPERS SHORT NOTES & REVIEW PAPERS, 1994, 33 (9B) :5463-5465
[8]   Cation ordering types and dielectric properties in the complex perovskite Ca(Ca1/3Nb2/3)O3 [J].
Levin, I ;
Chan, JY ;
Geyer, RG ;
Maslar, JE ;
Vanderah, TA .
JOURNAL OF SOLID STATE CHEMISTRY, 2001, 156 (01) :122-134
[9]  
RODRIGUEZCARVAJ.J, 1990, FULLPROF PROGRAMS RI
[10]   Development of low cost, high performance Ba(Zn1/3Nb2/3O3) based materials for microwave resonator applications [J].
Scott, RI ;
Thomas, M ;
Hampson, C .
JOURNAL OF THE EUROPEAN CERAMIC SOCIETY, 2003, 23 (14) :2467-2471