Mn(II)/O2-promoted oxidative annulation of vinyl isocyanides with boronic acids: synthesis of multi-substituted isoquinolines

被引：57
作者：
Wang, Hao [1 ]
Yu, Yang [1 ]
Hong, Xiaohu [1 ]
Xu, Bin [1 ,2 ,3 ]
机构：
[1] Shanghai Univ, Innovat Drug Res Ctr, Dept Chem, Shanghai 200444, Peoples R China
[2] Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China
[3] E China Normal Univ, Dept Chem, Shanghai Key Lab Green Chem & Chem Proc, Shanghai 200062, Peoples R China
来源：
CHEMICAL COMMUNICATIONS | 2014年 / 50卷 / 88期
基金：
中国国家自然科学基金;
关键词：
ELECTRON-DEFICIENT HETEROCYCLES; H BOND ACTIVATION; ONE-POT SYNTHESIS; ARYLBORONIC ACIDS; EFFICIENT ACCESS; MANGANESE(III) ACETATE; RADICAL ANNULATIONS; INTERNAL ALKYNES; IMIDOYL RADICALS; CARBON-MONOXIDE;
D O I：
10.1039/c4cc06427e
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
An efficient manganese(II)/O-2-promoted oxidative radical cascade reaction was developed for the modular synthesis of multi-substituted isoquinolines from easily accessible vinyl isocyanides and boronic acids.
引用
收藏
页码：13485 / 13488
页数：4
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