Mn(II)/O2-promoted oxidative annulation of vinyl isocyanides with boronic acids: synthesis of multi-substituted isoquinolines

被引：57

作者：

Wang, Hao ^{[1
]}

Yu, Yang ^{[1
]}

Hong, Xiaohu ^{[1
]}

Xu, Bin ^{[1
,2
,3
]}

机构：

[1] Shanghai Univ, Innovat Drug Res Ctr, Dept Chem, Shanghai 200444, Peoples R China

[2] Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China

[3] E China Normal Univ, Dept Chem, Shanghai Key Lab Green Chem & Chem Proc, Shanghai 200062, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2014年 / 50卷 / 88期

基金：

中国国家自然科学基金;

关键词：

ELECTRON-DEFICIENT HETEROCYCLES; H BOND ACTIVATION; ONE-POT SYNTHESIS; ARYLBORONIC ACIDS; EFFICIENT ACCESS; MANGANESE(III) ACETATE; RADICAL ANNULATIONS; INTERNAL ALKYNES; IMIDOYL RADICALS; CARBON-MONOXIDE;

D O I：

10.1039/c4cc06427e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An efficient manganese(II)/O-2-promoted oxidative radical cascade reaction was developed for the modular synthesis of multi-substituted isoquinolines from easily accessible vinyl isocyanides and boronic acids.

引用

页码：13485 / 13488

页数：4

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