Microstructure effects on BaTiO3/BaTi0.8Zr0.2O3 composites properties

被引:4
作者
Amaral, Thiago Martins [1 ]
Antonelli, Eduardo [3 ]
Alejandro Ochoa, Diego [2 ]
Eduardo Garcia, Jose [2 ]
Hernandes, Antonio Carlos [1 ]
机构
[1] Univ Sao Paulo, Phys Inst Sao Carlos, Grp Crescimento Cristais & Mat Ceram, BR-13560970 Sao Carlos, SP, Brazil
[2] Univ Politecn Cataluna, Dept Phys, BarcelonaTech, ES-08034 Barcelona, Spain
[3] Univ Fed Sao Paulo, UNIFESP, Sci & Technol Inst, Sao Jose Dos Campos, SP, Brazil
关键词
Sintering; Barium titanate; Layered ceramics; Dielectric; Ferroelectric and piezoelectric properties; MULTILAYER CERAMIC CAPACITORS; FREE PIEZOELECTRIC CERAMICS; DIELECTRIC-PROPERTIES; SOL-GEL; TEMPERATURE; INTERDIFFUSION; RELIABILITY; CONSTANTS; PRESSURE;
D O I
10.1016/j.ceramint.2016.02.071
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
The dielectric, pyroelectric and ferroelectric properties of bilayered BaTiO3/BaTi0.8Zr0.2O3 ceramics are described and correlated with their microstructure. Different sintering times are employed to change the microstructure and promote interdiffusion between the layers. The effects of constrained sintering on both compositions are analyzed and their properties are compared to that of single phase BaTiO3 and BaTi0.8Zr0.2O3 ceramics. The results show that, at sintering times until 2 h, the bilayer properties are predominantly affected by the presence of residual stresses. Only after 4 h sintering, the properties are predominantly affected by interdiffusion between the layers. (C) 2016 Elsevier Ltd and Techna Group S.r.l. All rights reserved.
引用
收藏
页码:8488 / 8494
页数:7
相关论文
共 35 条
[1]   Microstructural Features and Functional Properties of Bilayered BaTiO3/BaTi1-xZrxO3 Ceramics [J].
Amaral, Thiago Martins ;
Antonelli, Eduardo ;
Alejandro Ochoa, Diego ;
Eduardo Garcia, Jose ;
Hernandes, Antonio Carlos .
JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 2015, 98 (04) :1169-1174
[2]   BaTi1-xZrxO3 nanopowders prepared by the modified Pechini method [J].
Bernardi, M. I. B. ;
Antonelli, E. ;
Lourenco, A. B. ;
Feitosa, C. A. C. ;
Maia, L. J. Q. ;
Hernandes, A. C. .
JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 2007, 87 (03) :725-730
[3]  
CARRY C, 1986, J AM CERAM SOC, V69, pC215, DOI 10.1111/j.1151-2916.1986.tb07483.x
[5]  
Demartin M, 1997, J AM CERAM SOC, V80, P1079, DOI 10.1111/j.1151-2916.1997.tb02949.x
[6]   Effective elastic properties for unpoled barium titanate [J].
Dent, A. C. ;
Bowen, C. R. ;
Stevens, R. ;
Cain, M. G. ;
Stewart, M. .
JOURNAL OF THE EUROPEAN CERAMIC SOCIETY, 2007, 27 (13-15) :3739-3743
[7]   EFFECT OF A 2-DIMENSIONAL PRESSURE ON THE CURIE POINT OF BARIUM TITANATE [J].
FORSBERGH, PW .
PHYSICAL REVIEW, 1954, 93 (04) :686-692
[8]   RELAXOR BEHAVIOR OF BaZr0.2Ti0.8O3 CERAMICS WITH DIFFERENT GRAINS [J].
Fu, Chunlin ;
Pan, Fusheng ;
Cai, Wei ;
Deng, Xiaoling .
INTEGRATED FERROELECTRICS, 2008, 104 :1-7
[9]   INTERDIFFUSION AND KIRKENDALL EFFECT IN DOPED BARIUM TITANATE-STRONTIUM TITANATE DIFFUSION COUPLES [J].
GOPALAN, S ;
VIRKAR, AV .
JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 1995, 78 (04) :993-998
[10]  
Gopalan S, 1999, J AM CERAM SOC, V82, P2887, DOI 10.1111/j.1151-2916.1999.tb02173.x