Production and Analysis of the Physicochemical Properties of the Pyrolytic Oil Obtained from Pyrolysis of Different Thermoplastics and Plastic Mixtures

被引:13
作者
Palmay, Paul [1 ]
Haro, Carla [1 ]
Huacho, Ivan [1 ]
Barzallo, Diego [2 ,3 ]
Bruno, Joan Carles [4 ]
机构
[1] Escuela Super Politecn Chimborazo ESPOCH, Panamer Sur Km 1 1-2, Riobamba 060155, Ecuador
[2] Univ Estatal Milagro, Fac Ciencias & Ingn, Milagro 091050, Ecuador
[3] Univ Balearic Isl, Environm Analyt Chem Grp, Cra Valldemossa Km 7-5, Palma De Mallorca 07122, Spain
[4] Univ Rovira & Virgili, Dept Mech Engn, Ave Paisos Catalans 26, Tarragona 43007, Spain
关键词
pyrolysis; plastics waste; bio fuels; THERMAL-DEGRADATION; CATALYTIC PYROLYSIS; WASTE POLYSTYRENE; STYRENE RECOVERY; SLOW PYROLYSIS; FUEL; TEMPERATURE; KINETICS; OPTIMIZATION; TECHNOLOGIES;
D O I
10.3390/molecules27103287
中图分类号
Q5 [生物化学]; Q7 [分子生物学];
学科分类号
071010 ; 081704 ;
摘要
The constant search for the proper management of non-degradable waste in conjunction with the circular economy makes the thermal pyrolysis of plastics an important technique for obtaining products with industrial interest. The present study aims to produce pyrolytic oil from thermoplastics and their different mixtures in order to determine the best performance between these and different mixtures, as well as to characterize the liquid fraction obtained to analyze its use based on said properties. This was carried out in a batch type reactor at a temperature of 400 degrees C for both individual plastics and their mixtures, from which the yields of the different fractions are obtained. The liquid fraction of interest is characterized by gas chromatography and its properties are characterized by ASTM standards. The product of the pyrolysis of mixtures of 75% polystyrene and 25% polypropylene presents a yield of 82%, being the highest, with a viscosity of 1.12 cSt and a calorific power of 42.5 MJ/kg, which has a composition of compounds of carbon chains ranging between C6 and C20, for which it is proposed as a good additive agent to conventional fuels for industrial use.
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页数:17
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